Skip to main content
SpringerLink
Log in

Water-Soluble Luminescent Lanthanide Complexes Based on 2-Methacryloyloxyethyleniminodiacetic Acid Copolymers

  • CHEMISTRY
  • Published:
Doklady Chemistry Aims and scope Submit manuscript

Abstract

2-Methacryloyloxyethyleniminodiacetic acid and its new water-soluble copolymers with N-vinylpyrrolidone have been synthesized. The interaction of the copolymers in dilute aqueous solutions with lanthanide ions has been studied. The study has revealed the 25-fold amplification of Eu3+ luminescence in the polymer complex has been revealed as compared with a low-molecular-weight analog upon the formation of both heteroligand complexes with thenoyltrifluoroacetone and Eu3+ and Gd3+ heterometallic (bimetallic) complexes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Bünzli, J.-C.G., J. Lumin., 2016, vol. 170, no. 3, pp. 866–878. https://doi.org/10.1016/j.jlumin.2015.07.033

    Article  CAS  Google Scholar 

  2. Bünzli, J.-C.G., J. Coord. Chem., 2014, vol. 67, no. 23/24, pp. 3706–3733. https://doi.org/10.1080/00958972.2014.957201

    Article  CAS  Google Scholar 

  3. Bochkarev, M.N. and Pushkarev, A.P., Org. Photonics Photovolt., 2016, vol. 4, pp. 60–67. https://doi.org/10.1515/oph-2016-0007

    Article  Google Scholar 

  4. Utochnikova, V.V. and Kuzmina, N.P., Russ. J. Coord. Chem., 2016, vol. 42, no. 10, pp. 679–694. https://doi.org/10.7868/S0132344X16090073

    Article  CAS  Google Scholar 

  5. Karasev, V.E. and Petrochenkova, N.V., Lantanidsoderzhashchie polimery (Lanthanide-Containing Polymers), Vladivostok: Dal’nauka, 2005.

  6. Korshunov, M.A. and Mikhlin, V.S., Zh. Org. Khim., 1969, vol. 5, no. 2, pp. 254–256.

    CAS  Google Scholar 

  7. Tikhonova, L.I., Zh. Fiz. Khim., 1974, vol. 48, no. 4, pp. 823–827.

    CAS  Google Scholar 

  8. Latva, M., Takalo, H., Mukkala, V.-M., Matachescuc, C., Rodriguez-Ubisd, J.C., and Kankarea, J., J. Lumin., 1997, vol. 75, no. 2, p. 149. https://doi.org/10.1016/S0022-2313(97)00113-0

    Article  CAS  Google Scholar 

  9. Utochnikova, V.V., Coord. Chem Rev., 2019, vol. 398, p. 113006. https://doi.org/10.1016/j.ccr.2019.07.003

    Article  CAS  Google Scholar 

  10. Arnaud, N. and Georges, J., Spectrochim. Acta, 2003, vol. 59, no. 8, pp. 1829–1840. https://doi.org/10.1016/S1386-1425(02)00414-6

    Article  CAS  Google Scholar 

  11. Ermolaev V.L., Sveshnikova E.B. Rus. Chem. Rev., 2012, vol. 81, no. 9, pp. 769–789. https://doi.org/10.1070/RC2012v081n09ABEH004259

    Article  CAS  Google Scholar 

Download references

Funding

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (agreement no. 075–15–2020–794).

Author information

Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    T. N. Nekrasova, M. V. Solovskii, M. S. Borisenko, A. I. Fisher &  E. F. Panarin

  2. St. Petersburg State Technical University, 190013, St. Petersburg, Russia

    A. I. Fisher

Authors
  1. T. N. Nekrasova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. V. Solovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. S. Borisenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. I. Fisher
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. F. Panarin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. S. Borisenko.

Additional information

Translated by I. Kudryavtsev

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nekrasova, T.N., Solovskii, M.V., Borisenko, M.S. et al. Water-Soluble Luminescent Lanthanide Complexes Based on 2-Methacryloyloxyethyleniminodiacetic Acid Copolymers. Dokl Chem 497, 49–53 (2021). https://doi.org/10.1134/S0012500821030010

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0012500821030010

Keywords:

Search

Navigation