Skip to main content
SpringerLink
Log in

Selective Naked-Eye Fluorescein-Based Chemosensor for the Detection of Pd2+ Cations

  • CHEMISTRY
  • Published:
Doklady Chemistry Aims and scope Submit manuscript

Abstract

Highly sensitive and selective chemosensor for the determination of palladium(II) cations based on diphenylphosphino derivative of N-aminofluorescein was synthesized. The Pd2+ ion detection is accompanied by a contrast chromogenic “naked-eye” effect of the bright red coloration of an acetonitrile solution and an increase in the fluorescence intensity by 88 times.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Chen, X., Engle, K.M., Wang, D.H., et al., Angew. Chem., Int. Ed. Engl., 2009, vol. 48, pp. 5094–5115.

    Article  CAS  Google Scholar 

  2. Zeni, G. and Larock, R.C., Chem. Rev., 2004, vol. 104, pp. 2285–2310.

    Article  CAS  Google Scholar 

  3. Wiseman, C.L.S. and Zereini, F., Sci. Total Environ., 2009, vol. 407, pp. 2493–2500.

    Article  CAS  Google Scholar 

  4. Iavicoli, I., Fontana, L., and Bergamaschi, A., in: Encyclopedia of Environmental Health, 1st ed., Nriagu, J., Ed., Oxford: Elsevier, 2011, pp. 307–314.

    Google Scholar 

  5. Zhitenko, L.P., Kiseleva, I.N., and Khomutova, E.G., Inorg. Mater., 2016, vol. 52, pp. 1370–1376.

    Article  CAS  Google Scholar 

  6. Chen, X., Pradhan, T., Wang, F., et al., Chem. Rev., 2012, vol. 112, pp. 1910–1956.

    Article  CAS  Google Scholar 

  7. Ashwin, B.C.M.A., Sivaraman, G., Stalin, T., et al., J. Photochem. Photobiol. B, 2018, vol. 183, pp. 302–308.

    Article  CAS  Google Scholar 

  8. Chen, T., Wei, T., Zhang, Z., et al., Dyes Pigm., 2017, vol. 140, pp. 392–398.

    Article  CAS  Google Scholar 

  9. Zheng, H., Zhan, X.-Q., Bian, Q.-N., et al., Chem. Commun., 2013, vol. 49, pp. 429–447.

    Article  CAS  Google Scholar 

  10. Kaur, B., Kaur, N., and Kumar, S., Coord. Chem. Rev., 2018, vol. 358, pp. 13–69.

    Article  CAS  Google Scholar 

  11. Zhang, J., Zhang, L., Wei, Y., et al., Spectrochim. Acta A, 2014, vol. 122, pp. 731–736.

    Article  CAS  Google Scholar 

  12. Pearson, R.G., Coord. Chem. Rev., 1990, vol. 100, pp. 403–425.

    Article  CAS  Google Scholar 

  13. Crociani, B., Antonaroli, S., Burattini, M., et al., Dalton Trans., 2010, vol. 39, pp. 3665–3672.

    Article  CAS  Google Scholar 

  14. Liu, C., Huang, S., Yao, H., et al., RSC Adv., 2014, vol. 4, pp. 16109–16114.

    Article  CAS  Google Scholar 

  15. Gel’man, N.E., Terent’eva, N.A., Shanina, G.M., Kiparenko, L.M., and Rezl, V., Metody kolichestvennogo organicheskogo elementnogo mikroanaliza (Methods of Quantitative Organic Elemental Microanalysis), Moscow: Khimiya, 1987.

Download references

Funding

This work was supported by the State task of RF for 2020 (Southern Federal University). E.N. Shepelenko and A.D. Dubonosov worked in the framework of the State task   of the Southern Scientific Center of the RAS no. 01201354239.

Author information

Authors and Affiliations

  1. Department of Chemistry, Southern Federal University, 344006, Rostov-on-Don, Russia

    L. D. Popov & I. N. Shcherbakov

  2. Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia

    O. Yu. Karlutova, V. A. Bren &  V. I. Minkin

  3. Federal Research Center, Southern Scientific Center, Russian Academy of Sciences, 344006, Rostov-on-Don, Russia

    E. N. Shepelenko & A. D. Dubonosov

Authors
  1. L. D. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. Yu. Karlutova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. N. Shepelenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. D. Dubonosov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. N. Shcherbakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. A. Bren
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. I. Minkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. D. Dubonosov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Popov, L.D., Karlutova, O.Y., Shepelenko, E.N. et al. Selective Naked-Eye Fluorescein-Based Chemosensor for the Detection of Pd2+ Cations. Dokl Chem 490, 23–26 (2020). https://doi.org/10.1134/S0012500820020032

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0012500820020032

Keywords:

Search

Navigation