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Extraction of Cesium-137 and Americium-241 by Calix[n]arenes from Carbonate-Alkaline Media

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Abstract

Trends of cesium-137 and americium-241 extraction from carbonate–alkaline media with p-tert-butylcalix[n]arenes with macrocycles of different size (n = 4, 6, 8), including monofunctional derivatives with lipophilic substituents for increasing their solubility in organic media, were studied. It was demonstrated that O-n-octyl ethers of p-tert-butylcalix[6]arene appeared to be the most efficient extractants for Cs(I) cations, while it was p-tert-butylthiacalix[4]arene for and americium(III) cations.

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Authors and Affiliations

  1. Khlopin Radium Institute, St. Petersburg, 194021, Russia

    I. V. Smirnov, E. S. Stepanova & M. D. Karavan

  2. Ozersk Institute of Technology, Ozersk, Chelyabinsk oblast, 456783, Russia

    I. V. Smirnov, E. S. Stepanova, N. M. Ivenskaya, M. D. Karavan & S. R. Zaripov

  3. Saint-Petersburg State University, St. Petersburg, 199034, Russia

    I. V. Smirnov & M. D. Karavan

  4. Kazan (Volga Region) Federal University, Kazan, 420008, Russia

    S. R. Zaripov, S. E. Solovieva & I. S. Antipin

  5. A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, 420088, Russia

    S. E. Solovieva & I. S. Antipin

Authors
  1. I. V. Smirnov
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  2. E. S. Stepanova
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  3. N. M. Ivenskaya
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  4. M. D. Karavan
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  5. S. R. Zaripov
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  6. S. E. Solovieva
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  7. I. S. Antipin
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Corresponding author

Correspondence to I. V. Smirnov.

Additional information

Original Russian Text © I.V. Smirnov, E.S. Stepanova, N.M. Ivenskaya, M.D. Karavan, S.R. Zaripov, S.E. Solovieva, I.S. Antipin, 2018, published in Doklady Akademii Nauk, 2018, Vol. 479, No. 3, pp. 277–282.

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Smirnov, I.V., Stepanova, E.S., Ivenskaya, N.M. et al. Extraction of Cesium-137 and Americium-241 by Calix[n]arenes from Carbonate-Alkaline Media. Dokl Chem 479, 36–40 (2018). https://doi.org/10.1134/S0012500818030035

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  • DOI: https://doi.org/10.1134/S0012500818030035

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