Doklady Chemistry

, Volume 472, Issue 2, pp 30–35

Synthesis of 3-(2-hydroxyphenyl)-1,5-dialkyl-1H-1,2,4-triazoles and their Zn(II) complexes

  • I. E. Mikhailov
  • N. I. Vikrishchuk
  • L. D. Popov
  • A. D. Beldovskaya
  • G. A. Dushenko
  • Yu. V. Revinskii
  • V. I. Minkin
Chemistry

DOI: 10.1134/S0012500817020045

Cite this article as:
Mikhailov, I.E., Vikrishchuk, N.I., Popov, L.D. et al. Dokl Chem (2017) 472: 30. doi:10.1134/S0012500817020045
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Abstract

It has been demonstrated by 13C NMR and quantum-chemical calculations that alkylation of 5-(2-hydroxyphenyl)-3-methyl(vinylphenyl)-1H-1,2,4-triazoles with dialkyl sulfates in aqueous DMSO in the presence of alkali occurs exclusively in the 2-position of the triazole ring to give 3-(2-hydroxyphenyl)-1,5-dialkyl(alkylvinylphenyl)-1H-1,2,4-triazoles. Emission spectra of these compounds show two weak bands (λmaxfl = 317–346 and 430–447 nm, φ = 0.002–0.007), whereas their zinc complexes emit in the violet range of the visible spectrum (λmaxfl= 373–377 nm, φ = 0.20–0.25).

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • I. E. Mikhailov
    • 1
    • 2
  • N. I. Vikrishchuk
    • 3
  • L. D. Popov
    • 3
  • A. D. Beldovskaya
    • 1
  • G. A. Dushenko
    • 1
    • 2
  • Yu. V. Revinskii
    • 1
  • V. I. Minkin
    • 2
  1. 1.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  2. 2.Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia
  3. 3.Southern Federal UniversityRostov-on-DonRussia

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