Abstract
The electric-spark initiation of thermite mixtures based on nanosized powders of aluminum and copper oxide has been studied. Data on the effect of the electric spark discharge energy on the ignition delay were obtained. During the initiation of long cylindrical samples of mixtures with a low-current spark, two types of unsteady combustion were observed. The first type is characterized by the exponential establishment of constant burning rate. The second type is characterized by regions with incomplete reaction in the main propagation direction. To obtain steady combustion of a thermite mixture with a minimum ignition delay time, it is necessary to use a discharge energy of more than 5 mJ per 1 mm2 of the mixture surface.
REFERENCES
Energetic Nanomaterials. Synthesis, Characterization, and Application, Ed. by V. E. Zarko and A. A. Gromov (Elsevier, Amsterdam, 2016)
R. A. Yetter, “Progress towards Nanoengineered Energetic Materials," Proc. Combust. Inst. 38 (1), 57–81 (2021); DOI: 10.1016/j.proci.2020.09.008.
M. Polis, A. Stolarczyk, K. Glosz, and T. Jarosz, “Quo Vadis, Nanothermite? A Review of Recent Progress," Materials 15 (9), 3215 (2022); DOI: 10.3390/ma15093215.
S. F. Son, M. A. Hiskey, D. L. Naud, J. R. Busse, and B. W. Asay, “Lead-Free Electric Matches," in Proc. 29th Int. Pyrotech. Seminar, Westminster, IPSUSA, 2002, pp. 871–877.
S. Yu. Ananev, A. Yu. Dolgoborodov, A. A. Shiray, and B. D. Yankovsky, “Shock Initiation of Exothermic Reactions in Mechanically Activated Mixtures," J. Phys.: Conf. Ser. 774, 012069 (2016); DOI: 10.1088/1742-6596/774/1/012069.
S. Yu. Ananev, L. I. Grishin, A. Yu. Dolgoborodov, and B. D. Yankovskii, “Shock-Wave Initiation of a Thermite Mixture of Al + CuO," Fiz. Goreniya Vzryva 56 (2), 107–117 (2020) [Combust., Expl., Shock Waves 56 (2), 220–230 (2020); https://doi.org/10.1134/S0010508220020136].
A. Yu. Dolgoborodov, V. G. Kirilenko, M. A. Brazhnikov, L. I. Grishin, M. L. Kuskov, and G. E. Valyano, “Ignition of Nanothermites by a Laser Diode Pulse," Defense Technol. 18 (2), 194–204 (2022); DOI: 10.1016/j.dt.2021.01.006.
B. G. Popov, B. N. Verevkin, V. A. Bondar, and V. I. Gorshkov, Static Electricity in the Chemical Industry, Ed. by B. I. Sazhin (Khimiya, Leningrad, 1977) [in Russian].
S. Kumagai, Combustion (Ivanami Thetten, Tokio, 1976).
A. G. Ovcharenko and S. L. Rasko, “Evaluation of the Ignition Ability of Discharges in Electrification Processes," Polzunovskii Vestn., No. 3/1, 124–129 (2011).
W. L. Shaw, D. D. Dlott, R. A. Williams, and E. L. Dreizin, “Ignition of Nanocomposite Thermites by Electric Spark and Shock Wave," Propell., Explos., Pyrotech. 39 (3), 444–453 (2014); DOI: 10.1002/prep.201400027.
I. Monk, M. Schoenitz, and E. L. Dreizin, “Modes of Ignition of Powder Layers of Nanocomposite Thermites by Electrostatic Discharge," J. Energ. Mater. 35 (1), 29–43 (2017); DOI: 10.1080/07370652.2016.1150366.
M. I. Baranov, “Approximate Calculation of the Active Resistance of the Spark Discharge Plasma Channel in a High-Voltage Air Switch of Atmospheric Pressure," Visnik NTU KhPI, No. 15(1237), 5–11 (2017).
V. F. Tarasenko, E. Kh. Baksht, A. G. Burachenko, M. I. Lomaev, D. A. Sorokin, and Yu. V. Shut’ko, “On the Initiation of a Spark Discharge upon the Breakdown of Nitrogen and Air in a Nonuniform Electric Field," Zh. Tekh. Fiz. 80 (6), 151–154 (2010) [Tech. Phys. 55, 904–907 (2010); https://doi.org/10.1134/S1063784210060319].
A. N. Streletskii, I. V. Kolbanev, G. A. Vorobieva, A. Yu. Dolgoborodov, V. G. Kirilenko, and B. D. Yankovskii, “Kinetics of Mechanical Activation of Al/CuO Thermite," J. Mater. Sci. 53 (19), 13550–13559 (2018); DOI: 10.1007/s10853-018-2412-3.
B. D. Yankovsky, A. Yu. Dolgoborodov, L. I. Grishin, and S. Yu. Ananev, “Study of Combustion Wave Propagation in Linear Charges from Mechanically Activated Thermite Mixtures," J. Phys.: Conf. Ser. 1787, 012017 (2021); DOI: 10.1088/1742-6596/1787/1/012017.
Y. Wang, J. Dai, C. Wang, Y. Shen, J. Xu, and Y. Ye, “Study on the Combustion Mechanism of Al/CuO Nanothermites in Microtubes," in Proc. 44th Int. Pyrotech. Soc. Seminar, Tours, June 3–7, 2019, pp. 20–28.
A. Yu. Ananev, B. D. Yankovsky, and A. Yu. Dolgoborodov, “Qualitative Characteristics of the Results of Experimental Studies of Initiation and Combustion of Mechanically Activated Mixtures of Aluminum and Copper Oxide Powders," J. Phys.: Conf. Ser. 1147, 012035 (2019); DOI: 10.1088/1742-6596/1147/1/012035.
A. Dolgoborodov, B. Yankovsky, S. Ananev, G. Valyano, and G. Vakorina, “Explosive Burning of a Mechanically Activated Al and CuO Thermite Mixture," Energies 15 (2), 489 (2022); DOI: 10.3390/en15020489.
B. D. Yankovskii, C. Yu. Anan’ev, A. Yu. Dolgoborodov, L. I. Grishin, and G. S. Vakorina, “Ignition of a Gas Mixture by Combustion Products of the Al/CuO Thermite Composition," Gorenie Vzryv 15 (1), 72–81 (2022); DOI: 10.30826/CE22150109.
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Translated from Fizika Goreniya i Vzryva, 2023, Vol. 59, No. 4, pp. 85-92. https://doi.org/10.15372/FGV20230410.
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Dolgoborodov, A.Y., Yankovskii, B.D., Arsenov, P.A. et al. Electric-Spark Initiation of Nanothermites. Combust Explos Shock Waves 59, 471–478 (2023). https://doi.org/10.1134/S001050822304010X
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DOI: https://doi.org/10.1134/S001050822304010X