Abstract
Even a slight change in the content of impurity gases during a self-propagating high-temperature synthesis can lead to a change in the combustion regime and the characteristics of the target products. In this work, the dependence of the burning rate of Ti + C granular mixtures on a titanium particle size is determined for the first time, and the effect of impurity gas evolution when using various allotropic modifications of carbon (graphite/soot) is studied. Experimental results are analyzed using the convective–conductive combustion model, which explains the strong influence of impurity gas release on the front velocity. Interaction rate of the components becomes a key factor for granular mixtures in which the influence of impurity gases is leveled. Experiments show that the burning rates of granular mixtures of titanium with soot are noticeably higher than the burning rates of a mixture of titanium with graphite. The curves approximating the dependence of the burning rate of a granular mixture of titanium and graphite on the size of titanium particles correspond to the linear law of interaction of the initial components. The interaction in a mixture of titanium and soot occurs according to the parabolic law.
Similar content being viewed by others
REFERENCES
A. S. Rogachev and A. S. Mukasyan, Combustion for Material Synthesis (CRC Press Taylor & Francis Group, New York, 2015).
V. I. Vershinnikov and A. K. Filonenko, “Pressure Dependence of Rate of Gas-Free Combustion," Fiz. Goreniya Vzryva 14 (5), 42–47 (1978) [Combust., Expl., Shock Waves 14 (5), 588–592 (1978)].
L. J. Kecskes and A. Niiler, “Impurities in the Combustion Synthesis of Titanium Carbide," J. Am. Ceram. Soc. 72 (4), 655–661 (1989); DOI: 10.1111/j.1151-2916.1989.tb06190.x.
B. S. Seplyarskii, “Anomalous Dependence of Burning Rate of Gasless Systems on Diameter," Dokl. Akad. Nauk 396 (5), 640–643 (2004).
S. G. Vadchenko, “Effect of Thermal Treatment in Vacuum on Ignition of Titanium Compacts in Hydrogen," Int. J. Self-Propag. High-Temp. Synth. 19 (3), 206–208 (2010); DOI: 10.3103/S1061386210030064.
S. G. Vadchenko, “Effects of Obstacles on the Passage of Filtering Combustion Waves along a Porous Titanium Tape," Fiz. Goreniya Vzryva 55 (3), 43–49 (2019) [Combust., Expl., Shock Waves 55 (3), 282–288 (2019); DOI: 10.1134/S0010508219030055].
B. S. Seplyarskii and R. A. Kochetkov, “Granulation As a Tool for Stabilization of SHS Reactions," Int. J. Self-Propag. High-Temp. Synth. 26 (2), 134–136 (2017); DOI: 10.3103/S106138621702011X.
B. S. Seplyarsky, A. G. Tarasov, R. A. Kochetkov, and I. D. Kovalev, “Combustion Behavior of a Ti + TiC Mixture in a Nitrogen Coflow," Fiz. Goreniya Vzryva 50 (3), 61–67 (2014) [Combust., Expl., Shock Waves 50 (3), 300–305 (2014)].
A. P. Amosov, A. G. Makarenko, A. R. Samboruk, et al., “Effect of Batch Pelletizing on a Course of SHS Reactions: An Overview," Int. J. Self-Propag. High-Temp. Synth. 19 (1), 70–77 (2010); DOI: 10.3103/S1061386210010127.
B. S. Seplyarskii and R. A. Kochetkov, “A Study of the Characteristics of the Combustion of Ti + \(x\)C (\(x > 0.5\)) Powder and Granular Compositions in a Gas Coflow," Khim. Fiz. 36 (9), 23–31 (2017) [Russ. J. Phys. Chem. B 11, 798–807 (2017)]; DOI: 10.7868/S0207401X17090126.
B. S. Seplyarskii, R. A. Kochetkov, T. G. Lisina, et al., “Phase Composition and Structure of Titanium Carbide/Nickel Binder Synthesis Products," Neorg. Mater. 55 (11), 1169–1175 (2019) [Inorg. Mater. 55 (11), 1104–1110 (2019)]; DOI: 10.1134/S0002337X19110113.
S. Vorotilo, Ph. V. Kiryukhantsev-Korneev, B. S. Seplyarskii, et al., “(Ti,Cr)C-Based Cermets with Varied NiCr Binder Content via Elemental SHS for Perspective Cutting Tools," Crystals 10, 412–428 (2020); DOI: 10.3390/cryst10050412.
A. A. Zenin, A. G. Merzhanov, and G. A. Nersisyan, “Thermal Wave Structure in SHS Processes by the Example of Boride Synthesis," Fiz. Goreniya Vzryva 17 (1), 79–90 (1981) [Combust., Expl., Shock Waves 17 (1), 63–71 (1981)].
T. Šlȩzak, J. Zmywaczyk, and P. Koniorczyk, “Thermal Diffusivity Investigations of the Titanium Grade 1 in Wide Temperature Range," AIP Conf. Proc. 2170 (1), 020019 (2019); DOI: 10.1063/1.5132738.
S. V. Stankus et al., “Thermophysical Properties of MPG-6 Graphite," Teplofiz. Vys. Temp. 51 (2), 205–209 (2013) [High Temp. 51 (2), 179–182 (2013)].
I. A. Korol’chenko, A. V. Kazakov, A. S. Kukhtin, and V. L. Krylov, “Experimental Determination of Thermal Diffusivity of Materials," Pozharovzryvobezopasnost’ Veshchestv. Mater., No. 4, 36–38 (2021).
A. P. Aldushin, T. M. Martem’yanova, A. G. Merzhanov, et al., “Propagation of the Front of an Exothermic Reaction in Condensed Mixtures with the Interaction of the Components through a Layer of High-Melting Product," Fiz. Goreniya Vzryva 8 (2), 202–212 (1972) [Combust., Expl., Shock Waves 8 (2), 159–167 (1972)].
B. S. Seplyarskii, R. A. Kochetkov, and S. G. Vadchenko, “ Burning of the Ti + \(x\)C (\(1 > x > 0.5\)) Powder and Granulated Mixtures," Fiz. Goreniya Vzryva 52 (6), 51–59 (2016) [Combust., Expl., Shock Waves 52 (6), 51–59 (2016); DOI: 10.1134/S001050821606006X].
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Fizika Goreniya i Vzryva, 2022, Vol. 58, No. 3, pp. 110-116.https://doi.org/10.15372/FGV20220311.
Rights and permissions
About this article
Cite this article
Seplyarskii, B.S., Kochetkov, R.A., Lisina, T.G. et al. Macrokinetics of Combustion of Powder and Granular Titanium Mixtures with Different Allotropic Forms of Carbon. Combust Explos Shock Waves 58, 355–361 (2022). https://doi.org/10.1134/S001050822203011X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S001050822203011X