Abstract
Various macrokinetic modes of interaction (self-ignition or combustion) of compact samples from nonpassivated (pyrophoric) and passivated iron nanopowders with air are under study. Experiments show that the modes of interaction with air depend on the type of the used gaseous medium (argon or air), previously containing weighting cups with samples, and on how long the bottles remain in air. The possibility of passivation of pressed samples from pyrophoric iron nanopowder is experimentally established for the first time in the case where the weighting cups with samples remain in air. Various experimental methods are used to investigate the sample heating dynamics and the effect of density inhomogeneity along the length of the sample. It is revealed that pyrophoric samples are heated nonuniformly, although heating begins simultaneously over the entire surface of the sample.
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REFERENCES
J. Bouillard, A. Vignes, O. Dufaud, et al., “Ignition and Explosion Risks of Nanopowders," France J. Hazard. Mater. 181(1–3), 873–880 (2010); DOI: 10.1016/j.jhazmat.2010.05.094.
A. Pivkina, P. Ulyanova, Y. Frolov, et al., “Nanomaterials for Heterogeneous Combustion," Propell., Explos., Pyrotech.29 (1), 39 (2004); DOI: 10.1002/prep.200400025.
M. Hosokawa, K. Nogi, M. Naito, and T. Yokoyama,Nanoparticle Technology Handbook (Elsevier, 2007).
N. M. Rubtsov, B. S. Seplyarskii, and M. I. Alymov,Ignition and Wave Processes in Combustion of Solids(Springer, 2017).
M. Flannery, T. G. Desai, T. Matsoukas, et al., “Passivation and Stabilization of Aluminum Nanoparticles for Energetic Materials," Hindawi Publ. Corp. J. Nanomater. 2015, 185–199 (2008).
M. J. Meziani, C. E. Bunker, F. Lu, et al., “Formation and Properties of Stabilized Aluminum Nanoparticles," ACS Appl. Mater. Interfaces 13, 703–709 (2009); DOI: 10.1021/am800209m.
Nanoparticles: Synthesis, Stabilization, Passivation, and Functionalization, Ed. by R. Nagarajan and T. Alan Hatton (Am. Chem. Soc., Washington, 2008).
A. A. Gromov, Yu. I. Strokova, and A. A. Ditts, “Passivation Films on Particles of Electroexplosion Aluminum Nanopowders: A Review," Khim. Fiz. 29 (2), 77–91 (2010) [Russian J. Phys. Chem. B 4 (4), 156–169 (2010)].
Y.-S. Kwon, A. A. Gromov, and J. I. Strokova, “Passivation of the Surface of Aluminum Nanopowders by Protective Coatings of the Different Chemical Origin," Appl. Surf. Sci. 253, 5558–5564 (2007); DOI: 10.1016/j.apsusc.2006.12.124.
A. A. Gromov, U. Förter-Barth, and U. Teipel, “Aluminum Nanopowders Produced by Electrical Explosion of Wires and Passivated by Non-Inert Coatings: Characterisation and Reactivity with Air and Water," Powder Technol. 164, 111–115 (2006); DOI: 10.1016/j.powtec.2006.03.003.
M. I. Alymov, N. M. Rubtsov, B. S. Seplyarskii, et al., “Temporal Characteristics of Ignition and Combustion of Iron Nanopowders in the Air," Mendeleev Commun. 26, 452–454 (2016); DOI: 10.1016/j.mencom.2016.09.030.
M. I. Alymov, N. M. Rubtsov, B. S. Seplyarskii, et al., “Preparation and Characterization of Iron Nanoparticles Protected by an Oxide Film," Inorg. Mater. 53 (9), 911–915 (2017); DOI: 10.1134/S0020168517090011.
M. I. Alymov, N. M. Rubtsov, B. S. Seplyarskii, et al., “Passivation of Iron Nanoparticles at Subzero Temperatures," Mendeleev Commun. 27 (5), 482–484 (2017); DOI: 10.1016/j.mencom.2017.09.017.
M. I. Alymov, N. M. Rubtsov, B. S. Seplyarskii, et al., “Combustion and Passivation of Nickel Nanoparticles," Mendeleev Commun.27 (6), 631–633 (2017); DOI: 10.1016/j.mencom.2017.11.032.
O. B. Nazarenko, A. I. Sechin, and Y. A. Amelkovich, “Characterization of Naturally Aged Iron Nanopowder Produced by Electrical Explosion of Wires," Metals Mater. Int. (2019); DOI: 10.1007/s12540-019-00443-8.
A. V. Korshunov, “Kinetics of the Oxidation of an Electroexplosion Iron Nanopowder during Heating in Air," Khim. Fiz.31 (5), 27–35 (2012) [Russian J. Phys. Chem. B6 (3), 368–375 (2012)].
S. Dong, H. Cheng, H. Yang, et al., “Fabrication of Intermetallic NiAl by Self-Propagating High-Temperature Synthesis Reaction Using Aluminium Nanopowder under High Pressure," J. Phys.: Condens. Matter. 14, 11023–11030 (2002); DOI: 10.1088/0953-8984/14/44/421.
E. M. Hunt and M. L. Pantoya, “Ignition Dynamics and Activation Energies of Metallic Thermites: From Nano- to Micron-Scale Particulate Composites," J. Appl. Phys. 98, 034909 (2005); DOI: 10.1063/1.1990265.
F. Saceleanu, M. Idir, N. Chaumeix, and J. Z. Wen, “Combustion Characteristics of Physically Mixed 40 nm Aluminum/Copper Oxide Nanothermites Using Laser Ignition," Front. Chem., No. 6 (2018); DOI: 10.3389/fchem.2018.00465.
A. A. Gromov and U. Teipel, Metal Nanopowders: Production, Characterization, and Energetic Applications (John Wiley and Sons, 2014); DOI: 10.1002/9783527680696.
S. S. Kiparisov and G. A. Libenson, Powder Metallurgy (Metallurgiya, Moscow, 1991) [in Russian].
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Translated from Fizika Goreniya i Vzryva, 2021, Vol. 57, No. 3, pp. 79–87.https://doi.org/10.15372/FGV20210307.
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Alymov, M.I., Seplyarskii, B.S., Vadchenko, S.G. et al. Passivation of Compacted Samples Made of Pyrophoric Iron Nanopowders during Their Interaction with Air. Combust Explos Shock Waves 57, 326–333 (2021). https://doi.org/10.1134/S0010508221030072
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DOI: https://doi.org/10.1134/S0010508221030072