Abstract
The detonation properties of mechanically activated mixtures of ammonium perchlorate and aluminum were studied. The deflagration-to-detonation transition for low-density charges was investigated. Dependences of the detonation velocity of pressed charges with different types of aluminum on the activation time, density, and diameter of the charges were obtained. For compositions with nanosized aluminum, it is was found that the detonation velocity depends nonmonotonically on the inverse charge diameter and remains almost unchanged in a certain range of charge diameters. It is shown that the joint use of mechanical activation and nanosized components of the composite explosive significantly increases the detonability, reduces the critical diameter, and shifts the maximum of the detonation velocity as a function of density to higher charge densities.
Similar content being viewed by others
References
D. Price, “Contrasting Patterns in the Behavior of High Explosives,” in Proc. 11th Symp. (Int.) on Combustion (1967), pp. 693–702.
D. Price, A. R. Clairmont, and I. Jaffe, “The Detonation Behavior of Ammonium Perchlorate as a Function of Charge Density and Diameter,” NOLTR 67–71 (1967).
D. Price, A. R. Clairmont, and I. Jaffe, “Particle Size Effect on Explosive Behavior of Ammonium Perchlorate,” NOLTR 67-112 (1967).
D. Price, A. R. Clairmont, and J. O. Erkman, “Explosive Behavior of Aluminized Ammonium Perchlorate,” NOLTR 72-15 (1972).
M. F. Gogulya, M. N. Makhov, A. Yu. Dolgoborodov, et al., “Mechanical Sensitivity and Detonation Parameters of Aluminized Explosives,” Fiz. Goreniya Vzryva 40 (4), 82–95 (2004) [Combust., Expl. Shock Waves 40 (4), 445–457 (2004)].
P. Brousseau, H. E. Dorsett, M. D. Cliff, and C. J. Anderson, “Detonation Properties of Explosives Containing Nanometric Aluminium Powder,” in 12th Symp. (Int.) on Detonation, San Diego, August 11–16, 2002.
Jing Ping Lu, H. E. Dorsett, M. D. Franson, and M. D. Cliff, “Near-Field Performance Evaluations of ALEX Effect in Metalized Explosives,” DSTO-TR-1542 (2003).
A. N. Dremin, S. D. Savr, V. S. Trofimov, and K. K. Shvedov, Detonation Waves in Condensed Media (Nauka, Moscow, 1970), pp. 103–105 [in Russian].
M. F. Gogulya, M. N. Makhov, M. A. Brazhnikov, et al., “Explosive Characteristics of Aluminized HMX-Based Nanocomposites,” Fiz. Goreniya Vzryva 44 (2), 85–100 (2008) [Combust., Expl. Shock Waves 44 (2), 198–212 (2008)].
A. Yu. Dolgoborodov, “Mechanically Activated Oxidizer–Fuel Energetic Composites,” Fiz. Goreniya Vzryva 51 (1), 102–116 (2015) [Combust., Expl. Shock Waves 51 (1), 86–99 (2015)].
A. Yu. Dolgoborodov, N. E. Safronov, V. A. Teselkin, et al., “Mechanical Activation and Explosive Properties of Aluminum Mixtures with Ammonium Perchlorate,” Goreniye Vzryv 7, 384–388 (2014).
A. Yu. Dolgoborodov, A. A. Shevchenko, V. G. Kirilenko, and M. A. Brazhnikov, “Detonation of Pressed Charges of a Mechanically Activated Mixture of Ammonium Perchlorate and Aluminum,” Goreniye Vzryv 8 (2), 55–62 (2015).
A. A. Shevchenko, A. Yu. Dolgoborodov, V. G. Kirilenko, and M. A. Brazhnikov, “Detonation of Mixtures of Nano-Aluminum with Ammonium Perchlorate,” Goreniye Vzryv 9 (1), 83–90 (2016).
A. Ya. Apin, “Detonation and Explosive Combustion of Explosives,” Dokl. Akad. Nauk SSSR 50, 285–288 (1945).
A. Ya. Apin, I. M. Voskoboinikov, and G. S. Sosnova, “Reaction in the Detonation Wave of Composite Explosives,” Prikl. Mekh. Tekh. Fiz., No. 5, 115–117 (1963).
Yu. B. Khariton, Detonability of Explosives, in Problems of Explosives Theory (Izd. Akad. Nauk SSSR, Moscow–Leningrad, 1947), Book 1, pp. 7–29 [in Russian].
A. Ya. Apin, “On the Mechanism of Explosive Decomposition of Tetryl,” Dokl. Akad. Nauk SSSR XXIV (9), 922–924 (1939).
V. V. Andreev, A. P. Ershov, and L. A. Luk’yanchikov, “Two-Phase Low-Speed Detonation of a Porous Explosive,” Fiz. Goreniya Vzryva 20 (3), 89–93 (1984) [Combust., Expl. Shock Waves 20 (3), 330–334 (1984)].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Shevchenko, A.Yu. Dolgoborodov, V.G. Kirilenko, M.A. Brazhnikov.
Published in Fizika Goreniya i Vzryva, Vol. 53, No. 4, pp. 103–113, July–August, 2017.
Rights and permissions
About this article
Cite this article
Shevchenko, A.A., Dolgoborodov, A.Y., Kirilenko, V.G. et al. Detonation velocity of mechanically activated mixtures of ammonium perchlorate and aluminum. Combust Explos Shock Waves 53, 461–470 (2017). https://doi.org/10.1134/S0010508217040104
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0010508217040104