Abstract
Based on the previously developed model of detailed kinetics, the ignition delay time of two-fuel hydrogen–silane–air mixtures is calculated. The effect of the silane concentration and the temperature of the mixture on the ignition delay time is determined. It is shown that addition of a small (within 20%) amount of silane to the hydrogen–air mixture in the temperature range from 1200 to 2500 K leads to significant reduction of the ignition delay time of the mixture, whereas there is only a minor decrease in mixtures with silane concentrations higher than 20%.
Similar content being viewed by others
References
J. R. Chen, H. Y. Tsai, S. K. Chen, et al., “Analysis of a Silane Explosion in a Photovoltaic Fabricant Plant,” Process Saf. Prog. 25, 237–244 (2006).
Y. Y. Chang, D. J. Peng, H. C. Wu, et al., “Revising of a Silane Explosion in a Photovoltaic Fabrication Plant,” Process Saf. Prog. 26, 155–157 (2007).
D. A. Tropin and A. V. Fedorov, “Calculation of Flammability Limits of Silane–Oxygen and Silane–Air Mixtures,” Fiz. Goreniya Vzryva 52 (1), 46–51 (2016) [Combust., Expl., Shock Waves 52 (1), 40–44 (2016)].
C. J. Jachimowski and A. G. McLain, “A Chemical Kinetic Mechanism for the Ignition of Silane/Hydrogen Mixtures,” NASA Tech. Paper No. 2129 (1983).
A. G. McLain, C. J. Jachimowski, and R. C. Rogers, “Ignition of SiH4–H2–O2–N2 behind Reflected Shock Waves,” NASA Tech. Paper No. 2114, (1983).
W. Chinitz, “Theoretical Studies of the Ignition and Combustion of Silane–Hydrogen–Air Mixtures,” NASA Contractor Report No. 3876, (1985).
V. I. Golovitchev and C. Bruno, “Numerical Study of the Ignition of Silane/Hydrogen Mixtures,” J. Propul. Power 15 (1), 92–96 (1998).
D. A. Tropin and A. V. Fedorov, “Physicomathematical Modeling of Ignition and Combustion of Silane in Transient and Reflected Shock Waves,” Fiz. Goreniya Vzryva 51 (4), 37–45 (2015) [Combust., Expl., Shock Waves 51 (4), 431–438 (2015)].
J. A. Britten, J. Tong, and C. K. Westbrook, “A Numerical Study of Silane Combustion,” in Twenty-Third Symp. (Int.) on Combustion (The Combustion Inst., Pittsburgh, 1990), pp. 195–202.
A. V. Fedorov, P. A. Fomin, D. A. Tropin, and J. R. Chen, “Modeling of the Explosion Hazard and Alleviation of Explosion Consequences in Silane–Air Mixtures,” Izv. Vyssh. Uchebn. Zaved., Stroitelstvo, Nos. 9–10, 108–125 (2014).
A. V. Fedorov, P. A. Fomin, V. M. Fomin, D. A. Tropin, and J.-R. Chen, in Mathematical Analysis of Detonation Suppression by Inert Particles (Kao Tech, Kaohsiung, Taiwan, 2012).
A. V. Fedorov, P. A. Fomin, V. M. Fomin, et al., Physicomathemtical Modeling of Detonation Suppression by Clouds Consisting of Fine Particles (NGASU, Novosibirsk, 2011) [in Russian].
R. K. Cheng and A. K. Oppenheim, “Autoignition in Methane–Hydrogen Mixtures,” Combust. Flame 58, 125–139 (1984).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © D.A. Tropin, A.V. Fedorov.
Rights and permissions
About this article
Cite this article
Tropin, D.A., Fedorov, A.V. Ignition of a two-fuel hydrogen–silane mixture in air. Combust Explos Shock Waves 53, 1–7 (2017). https://doi.org/10.1134/S0010508217010014
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0010508217010014