Abstract
The autothermal regime of partial oxidation of carbonized coal residue in a stream of water-oxygen fluid at 923 K and 30 MPa is implemented for the first time. It is revealed that the oxidation of coal residue and the formation of combustible gases (hydrogen content in the products is increased by 26% with respect to its amount in the original sample) occur simultaneously and are caused by the participation of the H2O molecules in the redox reactions.
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References
G. Brunner, “Supercritical Process Technology Related to Energy and Future Directions—an Introduction,” J. Supercrit. Fluids 96, 11–20 (2015).
A. A. Vostrikov, O. N. Fedyaeva, D. Yu. Dubov, S. A. Psarov, and M. Ya. Sokol, “Conversion of Brown Coal in Supercritical Water Without and with Addition of Oxygen at Continuous Supply of Coal–Water Slurry,” Energy 36, 1948–1955 (2011).
O. N. Fedyaeva, A. A. Vostrikov, A. V. Shishkin, M. Ya. Sokol, N. I. Fedorova, and V. A. Kashirtsev, “Hydrothermolysis of Brown Coal in Cyclic Pressurization-Depressurization Mode,” J. Supercrit. Fluids 62, 155–164 (2012).
A. A. Vostrikov, D. Yu. Dubov, S. A. Psarov, and M. Ya. Sokol, “Oxidation of a Coal Particle in Flow of Supercritical Aqeous Fluid,” Fiz. Goreniya Vzryva 44 (2), 23–31 (2008) [Combust., Expl., Shock Waves 44 (2), 141–149 (2008)].
A. A. Vostrikov, O. N. Fedyaeva, A. V. Shishkin, and M. Ya. Sokol, “Combustion of Carbonized Coal Residue in a Mixture of Ammonium Nitrate and Supercritical Water,” Fiz. Goreniya Vzryva 50 (2), 132–134 (2014) [Combust., Expl., Shock Waves 50 (2), 242–244 (2014)].
K. J. Huttinger and W. F. Merdes, “The Carbon-Steam Reaction at Elevated Pressure: Formations of Product Gases and Hydrogen Inhibitions,” Carbon 30 (6), 883–894 (1992).
J. L. Johnson, “Fundamentals of Coal Gasification. Ch. 23,” in Chemistry of Coal Utilization, Second Suppl. Vol., Ed. by M. A. Elliot (John Wiley and Sons Inc., New York, 1981).
Perry’s Chemical Engineers’ Handbook, Ed. by R. H. Perry, D. W. Green, and J. O. Maloney (McGraw-Hill, New York, 1997).
E. W. Lemmon, M. O. McLinden, and D. G. Friend, Thermophysical Properties of Fluid Systems. NIST Chemistry WebBook, NIST Standard Reference Database No. 69, Ed. by P. J. Linstrom and W. G. Mallard (Nat. Inst. of Standards and Technology, Gaithersburg, Maryland); http://webbook.nist.gov/chemistry/fluid/.
Y. Li, L. Guo, X. Zhang, H. Jin, and Y. Lu, “Hydrogen Production from Coal Gasification in Supercritical Water with a Continuous Flowing System,” Int. J. Hydrogen Energy 35, 3036–3045 (2010).
R. Zhang, W. Jiang, L. Cheng, B. Sun, D. Sun, and J. Bi, “Hydrogen Production from Lignite via Supercritical Water in Flow Reactor,” Int. J. Hydrogen Energy 35, 11810–11815 (2010).
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Original Russian Text © A.A. Vostrikov, O.N. Fedyaeva, D.Yu. Dubov, A.V. Shishkin, M.Ya. Sokol.
Published in Fizika Goreniya i Vzryva, Vol. 52, No. 5, pp. 75–78, September–October, 2016.
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Vostrikov, A.A., Fedyaeva, O.N., Dubov, D.Y. et al. Combustion of carbonized coal residue in water–oxygen supercritical fluid. Combust Explos Shock Waves 52, 562–565 (2016). https://doi.org/10.1134/S0010508216050075
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DOI: https://doi.org/10.1134/S0010508216050075