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Skeletal mechanism of inhibition and suppression of a hydrogen flame by addition of trimethylphosphate

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Combustion, Explosion, and Shock Waves Aims and scope

Abstract

A skeletal mechanism of inhibition and suppression of H2/O2/N2 by addition of trimethylphosphate was developed. It includes a mechanism of hydrogen oxidation (13 elementary steps involving 7 species) and two elementary reactions involving trimethylphosphate and its conversion products. This skeletal mechanism adequately predicts the burning velocity of flames with added inhibitor in the range of equivalence ratios studied, and can be used to model fire suppression.

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Authors and Affiliations

  1. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    O. P. Korobeinichev, V. M. Shvartsberg & A. G. Shmakov

  2. Novosibirsk State University, Novosibirsk, 630090, Russia

    A. G. Shmakov

Authors
  1. O. P. Korobeinichev
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  2. V. M. Shvartsberg
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  3. A. G. Shmakov
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Corresponding author

Correspondence to V. M. Shvartsberg.

Additional information

Original Russian Text © O.P. Korobeinichev, V.M. Shvartsberg, A.G. Shmakov.

Published in Fizika Goreniya i Vzryva, Vol. 50, No. 3, pp. 3–8, May–June, 2014.

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Korobeinichev, O.P., Shvartsberg, V.M. & Shmakov, A.G. Skeletal mechanism of inhibition and suppression of a hydrogen flame by addition of trimethylphosphate. Combust Explos Shock Waves 50, 245–250 (2014). https://doi.org/10.1134/S0010508214030010

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  • DOI: https://doi.org/10.1134/S0010508214030010

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