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Using ethanol for preparation of nanosized TiO2 by gaseous detonation

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Combustion, Explosion, and Shock Waves Aims and scope

Abstract

A method of preparing nanosized titanium dioxide by gaseous detonation by using ethanol, hydrogen, and oxygen as an explosion source and titanium tetrachloride as a precursor is described. The results indicate that the rutile phase content of the obtained products is high, and the pure rutile phase can be produced by adding a small amount of hydrogen. Most of the particles obtained under the two different synthesis conditions are spherical (or sphere-like) with small and even particle sizes, generally about 30 nm, and has a very good size dispersion.

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References

  1. W. Li, C. Ni, H. Lin, et al., “Size Dependence of Thermal Stability of TiO2 Nanoparticles,” Appl. Phys. 96(11), 6663–6668 (2004).

    Article  Google Scholar 

  2. P. P. Ahonen, U. Tapper, E. I. Kauppinen, et al., “Aerosol Synthesis of Ti-O Powders Via In-Droplet Hydrolysis of Titanium Alkoxide,” Mater. Sci. Eng. A 315(1/2), 113–121 (2001).

    Article  Google Scholar 

  3. T. Tsumura, N. Kojitani, I. Izumi, et al., “Carbon Coating of Anatase-Type and Photoacitivity,” Mater. Chem. 12(5), 1391–1396 (2002).

    Article  Google Scholar 

  4. P. Sujaridworakun, F. Koh, T. Fujiwara, et al., “Preparation of Anatase Nanocrystals Deposited on Hydroxyapatite by Hydrothermal Treatment,” Mater. Sci. Eng. C 25(1), 87–91 (2005).

    Article  Google Scholar 

  5. X. W. Bao, S. S. Yan, F. Chen, et al., “Preparation of TiO2 Photocatalyst by Hydrothermal Method from Aqueous Peroxotitanium Acid Gel,” Mater. Lett. 59(4), 412–415 (2005).

    Article  Google Scholar 

  6. H. Z. Zhang and J. F. Banfield, “Understanding Polymorphic Phase Transformation Behavior During Growth of Nanocrystalline Aggregates: Insights from TiO2,” Phys. Chem. B 104(15), 3481–3487 (2000).

    Article  Google Scholar 

  7. X. J. Li, X. Ouyang, H. H. Yan, et al., “Detonation Synthesis of TiO2 Nanoparticles in Gas Phase,” Adv. Mater. Res. 32, 13–16 (2008).

    Article  Google Scholar 

  8. X. Quyang, X. Li, H. H. Yan, Y. D. Qu, and F. Mo, “Synthesis of TiO2 Nanoparticles from Sprayed Droplets of Titanium Tetrachloride by the Gas-Phase Detonation Method,” Fiz. Goreniya Vzryva 44(5), 112–116 (2008) [Combust., Expl., Shock Waves 44 (5), 597–600 (2008)].

    Google Scholar 

  9. Y. D. Qu, X. J. Li, Zh. Zhao, and G. Sun, “Titania Nanocrystalline Prepared by Detonation Method and Calculation of Detonation Parameters,” Propel., Expl., Pyrotech. 36, 75–79 (2011).

    Google Scholar 

  10. K. A. Spuur and H. Myers, “Quantitatice Analysis of Anatase-Rutile Mixtures with X-ray Diffractometer,” Anal. Chem. (1957).

    Google Scholar 

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Correspondence to H. H. Yan.

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Original Russian Text © H.H. Yan, X.C. Huang, S.X. Xi.

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Translated from Fizika Goreniya i Vzryva, Vol. 50, No. 2, pp. 77–80, March–April, 2014.

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Yan, H.H., Huang, X.C. & Xi, S.X. Using ethanol for preparation of nanosized TiO2 by gaseous detonation. Combust Explos Shock Waves 50, 192–195 (2014). https://doi.org/10.1134/S0010508214020105

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  • DOI: https://doi.org/10.1134/S0010508214020105

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