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Phosphorus-containing iminoxyl and nitroxyl free radicals as promising spin labels

  • Molecular Biophysics
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Abstract

The structure and magnetic parameters of a series of nitroxyl and iminoxyl radicals differing in the position of the P atom with respect to the radical center were established by EPR. Free radicals were obtained in chemical and electrochemical reactions and also through UV irradiation with the use of spin traps. The phosphononitroxyls and phosphonoiminoxyls have proved quite sensitive to the milieu and temperature, which makes them promising spin labels for biological objects.

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References

  1. A. V. Il’yasov, A. A. Vafina, I. D. Morozova, and M. B. Zuev, EPR Spectra and Stereochemistry of Phosphorous Free Radicals (Nauka, Moscow, 1985) [in Russian].

    Google Scholar 

  2. A. I. Mikhaleva, A. B. Zaitsev, and B. A. Trofimov, Uspekhi Khimii 75, 884 (2005).

    Google Scholar 

  3. H. M. Z. Osborn, N. Gummele, and L. M. Harwood, J. Chem. Soc., Perkin Trans. 1, 2419 (2002).

    Article  Google Scholar 

  4. V. M. Peshkova, V. M. Savostina, and K. E. Ivanova, Oximes (Nauka, Moscow, 1977) [in Russian].

    Google Scholar 

  5. M. P. Sokolov and B. I. Buzykin, Zh. Obshch. Khimii 61, 1267 (1991).

    Google Scholar 

  6. A. V. Il’yasov, A. A. Vafina, E. Breuer, and G. Hagele, Appl. Magn. Reson. 14, 489 (1998).

    Article  Google Scholar 

  7. V. I. Morozov, B. I. Buzykin, and A. V. Il’yasov, Russ. Chem. Bull. Int. Edn. 54(2), 342 (2005).

    Article  Google Scholar 

  8. Ya. A. Levin, A. V. Il’yasov, I. D. Morozova, et al., Bull. Acad. Sci. USSR, Div. Chem. Sci. 24(2), 314 (1975).

    Article  Google Scholar 

  9. A. Sh. Mukhtarov, A. V. Il’yasov, Ya. A. Levin, and M. S. Skorobogatova, Bull. Acad. Sci. USSR, Div. Chem. Sci. 25(12), 2625 (1976).

    Article  Google Scholar 

  10. A. V. Il’yasov and Vu. M. Kargin, Magn. Res. Rev. 16, 135 (1993).

    Google Scholar 

  11. A. L. Buchachenko and A. M. Vasserman, Stable Radicals (Khimiya, 1973) [in Russian].

    Google Scholar 

  12. A. V. Il’yasov, Ya. A. Levin, A. Sh. Mukhtarov, and M. S. Skorobogatova, Theor. Exp. Chem. 11, 515 (1975).

    Article  Google Scholar 

  13. A. Sh. Mukhtarov, A. V. Il’yasov, Ya. A. Levin, et al., Theor. Exp. Chem. 12, 656 (1976).

    Article  Google Scholar 

  14. C. Reichardt, Angew. Chem. 4, 29 (1965).

    Article  Google Scholar 

  15. A. V. Il’yasov, Ya. A. Levin, A. Sh. Mukhtarov, and M. S. Skorobogatova, Bull. Acad. Sci. USSR, Div. Chem. Sci. 24(7), 1545 (1975).

    Article  Google Scholar 

  16. T. A. Zyablikova, Doctoral Dissertation in Chemistry (Inst. Org. Phys. Chem., Kazan, 1999).

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Authors and Affiliations

  1. Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, 420088, Russia

    A. V. Il’yasov

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  1. A. V. Il’yasov
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Correspondence to A. V. Il’yasov.

Additional information

Original Russian Text © A.V. Il’yasov, 2013, published in Biofizika, 2013, Vol. 58, No. 2, pp. 233–238.

The experimental data contained herein fully correspond to the Russian-language publication but the text has been revised for the English version. A.G.

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Il’yasov, A.V. Phosphorus-containing iminoxyl and nitroxyl free radicals as promising spin labels. BIOPHYSICS 58, 167–171 (2013). https://doi.org/10.1134/S0006350913020103

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