Abstract
The results of continuous minute measurements of the surface concentrations of ozone, nitric oxide, nitrogen dioxide, carbon monoxide, and sulfur dioxide during the 2002–2004 period at the environmental station of the Oboukhov Institute of Atmospheric Physics, Russian Academy of Sciences (IAP), and the Faculty of Geography, Moscow State University (MSU), are discussed. It is shown that the conditions of Moscow’s southwestern region remote from large local pollution sources reflect the general regularities of the variability of trace gases in an urban atmosphere. This is manifested in the mean annual value of the ratio NO/NO2 (a little less than 1), decreased daylight values of O3, increased values of the rest of the trace gases as compared to the background region, and the presence of a secondary nocturnal maximum in the diurnal cycle of O3. The features of the annual and diurnal cycles of the concentrations of the substances under analysis are discussed. In the diurnal cycle of the primary products of combustion (NO and CO), an excess of the morning maximum (over the evening one) is observed during both warm and transition periods and higher values of the night maximum (as compared to the daylight one) are noted for summer. The temperature stratification properties determined from the MSU long-term acoustic sounding data serve as a possible cause for both of the effects revealed. The annual cycle of the concentration of surface ozone is characterized by the highest values for spring and summer. The annual cycles of NO, NO2, CO, and SO2 do not demonstrate any obvious seasonal regularities. A significant seasonal variation of the ratio NO/NO2, which is associated with the oxidizing properties of the urban atmosphere, is revealed. The record high concentrations of trace gases in the atmosphere over Moscow are given, and the meteorological conditions for their accumulation are discussed.
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References
A. S. Britaev, “Ozone Climate of a Large City,” in Proceedings of Conference “Climate—City—Man: Control of Urban Environmental Pollution (Gidrometeoizdat, Moscow, 1977), pp. 141–146 [in Russian].
Climate, Weather, Ecology of Moscow, Ed. by F. Ya. Klinov (Gidrometeoizdat, St. Petersburg, 1995) [in Russian].
V. I. Dianov-Klokov, “Spectroscopic Studies of Air Pollution over Large Cities,” Izv. Akad. Nauk SSSR, Fiz. Atmos. Okeana 20, 883–900 (1984).
N. F. Elanskii and O. I. Smirnova, “Ozone and Nitrogen Oxide Concentrations in the Atmospheric Surface Layer over Moscow,” Izv. Akad. Nauk. Fiz. Atmos. Okeana 33, 597–611 (1997) [Izv., Atmos. Ocean. Phys. 33, 551–564 (1997)].
A. M. Zvyagintsev and I. N. Kuznetsova, “Surface Ozone Variations in Moscow Environs: The Results of Continuous Ten-Year Observations,” Izv. Akad. Nauk. Fiz. Atmos. Okeana 38, 486–495 (2002) [Izv., Atmos. Ocean. Phys. 38, 431–439 (2002)].
A. M. Zvyagintsev, I. B. Belikov, V. I. Egorov, et al., “Positive Anomalies in the Surface Ozone Concentration in July–August 2002 over Moscow and Its Suburbs,” Izv. Akad. Nauk. Fiz. Atmos. Okeana 40, 78–89 (2004) [Izv., Atmos. Ocean. Phys. 40, 68–79 (2004)].
M. A. Lokoshchenko, N. V. Semenova, A. A. Isaev, et al., “Use of Acoustic Sounding for Studies of Raised Inversions and Their Influence on Pollution in the Lower Atmosphere,” in Proceedings of XV Session of the Russian Acoustical Society (Nizhni Novgorod, 2004), Vol. 2, pp. 117–121 [in Russian].
N. F. Elansky, T. A. Markova, I. B. Belikov, and E. A. Oberlander, “Transcontinental Observations of Surface Ozone Concentration in the TROICA Experiments: 1. Space and Time Variability,” Izv. Atmos. Ocean. Phys. 37(Suppl. 1), S24–S38 (2001).
N. F. Elansky, M. A. Lokoshchenko, N. N. Sarana, et al., “Diurnal and Annual Cycles of Air Pollution over Moscow,” Vestn. Mosk. Univ., Ser. 5: Geograph., No. 1, 29–35 (2006).
M. A. Lokoshchenko and N. F. Elansky, “Dynamics of Surface-Air Pollution during the Passage of a Cold Front,” Izv. Akad. Nauk. Fiz. Atmos. Okeana 42, 167–175 (2006) [Izv., Atmos. Ocean. Phys. 42, 148–155 (2006)].
C. Appenzeller, J. R. Holton, and K. H. Rosenlof, “Seasonal Variation of Mass Transport across the Tropopause,” J. Geophys. Res. D 101, 15 071–15 078 (1996).
P. J. Crutzen and P. H. Zimmerman, “The Changing Photochemistry of the Troposphere,” Tellus, A, B 43, 136–151 (1991).
A. M. Zvyagintsev, “Major Characteristics of Variations in the Ozone Content in the Lower Troposphere over Europe,” Meteorol. Gidrol., No. 10, 46–56 (2004).
F. Ya. Rovinskii and V. I. Egorov, Ozone and Nitrogen and Sulfide Oxides in the Lower Atmosphere (Gidrometeoizdat, Leningrad, 1986) [in Russian].
E. Yu. Bezuglaya, Meteorological Potential and Climatic Features in Urban Air Pollution (Gidrometeoizdat, Leningrad, 1980) [in Russian].
T. A. Markova, N. F. Elansky, I. B. Belikov, et al., “Distribution of Nitrogen Oxides in the Atmospheric Surface Layer over Coninental Regions of Russia,” Izv. Akad. Nauk. Fiz. Atmos. Okeana 40, 796–808 (2004) [Izv., Atmos. Ocean. Phys. 40, 713–724 (2004)].
T. R. Oke, Climates of the Boundary Layer (Gidrometeoizdat, Leningrad, 1982) [in Russian].
S. G. Paramonov, Background Pollution of the Atmosphere over European Russia, Candidate’s Dissertation in Geographical Sciences (MSU, Moscow, 1994).
Mobile Laboratory for Environmental Observations, Ed. by N. F. Elansky (Bonaekspo, Moscow, 2005) [in Russian].
Survey of the Background State of the Natural Environment in the CIS Area over 1998 and Its Dynamics over the Past Decade, Ed. by Yu. A. Izrael’ and F. Ya., Rovinskii (Gidrometeoizdat, St. Petersburg, 1999) [in Russian].
T. E. Graedel and P. J. Crutzen, Atmospheric Change: An Earth System Perspective (Freeman, New York, 1993).
Handbook on Ecological and Climatic Characteristics of the City of Moscow, Ed. by A. A. Isaev (Mosk. Gos. Univ., Moscow, 2003) [in Russian].
E. Yu. Bezuglaya, G. P. Rastorgueva, and I. V. Smirnova, What Does an Industrial City Breathe? (Gidrometeoizdat, Leningrad, 1991) [in Russian].
Bulletin of Air Pollution in the City of Moscow over 2004 (Mosekomonitoring, Moscow, 2005) [in Russian].
P. A. Kratzer, Urban Climate (Inostrannaya Literatura, Moscow, 1958) [in Russian].
M. A. Kallistratova, H.-R. Lehmann, J. Neisser, et al., Erste ergebnisse von messungen mit einem Vertical-SODAR. Z. Meteorol. 36, 229–237 (1986).
M. A. Lokoshchenko, “Use of Vertical Sodars in Meteorology (A Review),” Opt. Atmos. Okeana 9, 970–992 (1996) [Atmos. Ocean. Opt. 9, 616–628 (1996)].
M. A. Lokoshchenko, “Long-TErm Sodar Observations in Moscow and a New Approach of the Potential Mixing Determination by Radiosonde Data,” J. Atmos. Ocean. Technol. 19, 1151–1162 (2002).
M. A. Lokoshchenko, N. Ph. Elansky, and N. V. Semenova, “Influence of Thermal Stratification on Morning Growth of Surface Ozone,” in Proceedings of 12th International Symposium on Acoustic Remote Sensing (United Kingdom, Cambridge, 2004), Addendum, pp. 27–30.
J. H. Seinfeld and S. N. Pandis, Atmospheric Chemistry and Physics. From Air Pollution to Climate Change (Wiley, New York, 1997).
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Original Russian Text © N.F. Elansky, M.A. Lokoshchenko, I.B. Belikov, A.I. Skorokhod, R.A. Shumskii, 2007, published in Izvestiya AN. Fizika Atmosfery i Okeana, 2007, Vol. 43, No. 2, pp. 246–259.
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Elansky, N.F., Lokoshchenko, M.A., Belikov, I.B. et al. Variability of trace gases in the atmospheric surface layer from observations in the city of Moscow. Izv. Atmos. Ocean. Phys. 43, 219–231 (2007). https://doi.org/10.1134/S0001433807020089
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DOI: https://doi.org/10.1134/S0001433807020089