Abstract
Electron spin resonance on samarium ions with stabilized valence Sm3+ is investigated in the fluctuating-valence semiconductor SmB6, both pure and doped with the rare-earth ions Eu2+, Er3+, and Gd3+. The dynamic and static Jahn-Teller effects have been observed for the first time on rare-earth ions. The relation between the Jahn-Teller effect in a fluctuating-valence semiconductor and the excitonic nature of the ground state of such a semiconductor is discussed.
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D. I. Khomskii, Usp. Fiz. Nauk 129, 443 (1979) [Sov. Phys. Usp. 22, 879 (1979)].
T. S. Al’tshuler, G. G. Khaliullin, and D. I. Khomski Zh. Éksp. Teor. Fiz. 90, 2104 (1986) [Sov. Phys. JETP 63, 1234 (1986)].
G. Wiese, H. Schaeffer, and B. Elschner, Europhys. Lett. 11, 791 (1990).
S. A. Al’tshuler and B. M. Kozyrev, Electronic Paramagnetic Resonance (Academic Press, New York, 1964) [Russian original, Nauka, Moscow, 1972].
H. Sturm, B. Elschner, and K. H. Hoeck, Phys. Rev. Lett. 54, 1291 (1985).
H. Sturm, Dissertation, Darmstadt (1985).
T. S. Altshuler and M. S. Bresler, Czech. J. Phys. 46, Suppl. S4, 1985 (1996).
T. S. Al’tshuler and M. S. Bresler, JETP Lett. 66, 681 (1997).
.S. Altshuler, V. N. Mironov, and M. M. Zaripov, J. Phys. 15, 3785 (1982).
S. Kunii, T. Uemura, Y. Chiba, T. Kasuya, and M. Date, J. Magn. Magn. Mater. 52, 271 (1985).
T. Uemura, Y. Chiba, M. Hagiwara, and M. Date, J. Phys. Soc. Jpn. 55, 3737 (1986).
S. V. Demishev, A. V. Semeno, N. E. Sluchanko, N. A. Samarin, J. Singleton, A. Ardavan, S. J. Blundell, W. Hayes, and S. Kunii, JETP Lett. 64, 760 (1996).
M. Kasaya, H. Kimura, Y. Isikawa, T. Fujita, and T. Kasuya, in Valence Fluctuations in Solids, edited by L. M. Falicov, W. Hanke, and M. B. Maple (North Holland, Amsterdam, 1981, p. 251).
A. Abragam and B. Bleaney, Electron Paramagnetic Resonance of Transition Ions (Clarendon Press, Oxford, 1970) [Russian translation, Vols. 1, 2, Mir, Moscow, 1972, 1973].
A. A. Antipin, I. N. Kurkin, L. Z. Potvorova, and L. Ya. Shekun, Fiz. Tverd. Tela (Leningrad) 7, 3209 (1965) [Sov. Phys. Solid State 7, 2596 (1965)].
P. Nyhus, S. L. Cooper, Z. Fisk, and J. Sarrao, Phys. Rev. 55, 12488 (1997).
I. B. Bersuker, Electronic Structure and Properties of Coordination Compounds (Khimiya, Leningrad, 1976, p. 195).
C. Weber, E. Sigmund, and M. Wagner, Phys. Status Solidi B 138, 661 (1986).
K. A. Kikoin and A. S. Mishchenko, Zh. Éksp. Teor. Fiz. 104, 3810 (1993) [JETP 77, 828 (1993)].
P. A. Alekseev, A. S. Ivanov, B. Dorner et al., Europhys. Lett. 10, 457 (1989).
P. A. Alekseev, A. S. Ivanov, V. N. Lazukov et al., Physica 180–181, 281 (1992).
K. A. Kikoin, Zh. Éksp. Teor. Fiz. 85, 1000 (1983) [Sov. Phys. JETP 58, 582 (1983)].
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Zh. Éksp. Teor. Fiz. 115, 1860–1871 (May 1999)
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Al’tshuler, T.S., Bresler, M.S. Jahn-Teller effect on Sm3+ ions in SmB6 . J. Exp. Theor. Phys. 88, 1019–1025 (1999). https://doi.org/10.1134/1.558885
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DOI: https://doi.org/10.1134/1.558885