Skip to main content
Log in

Structural transition in small gas-like clusters

  • Fluids
  • Published:
Journal of Experimental and Theoretical Physics Aims and scope Submit manuscript

Abstract

We propose a model, which is an alternative to the droplet model and presumes that the number of bonds between the atoms is a minimum, to describe highly excited clusters containing a small number of atoms. It is shown that at sufficiently high temperatures such a structure, which has the form of a system of spontaneously appearing chains of atoms (virtual chains),is realized with a greater probability than the close-packed structure. Analytic estimates are supported by the results of numerical molecular-dynamics simulations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. I. I. Frenkel’, Kinetic Theory of Liquids, Clarendon Press, Oxford (1946).

    Google Scholar 

  2. Ya. B. Zel’dovich, Zh. Éksp. Teor. Fiz. 12, 525 (1942).

    Google Scholar 

  3. R. S. Dumont, S. Jain, and A. G. Basile, J. Chem. Phys. 102, 4227 (1995).

    Article  ADS  Google Scholar 

  4. D. I. Zhukhovitskii, Zh. Éksp. Teor. Fiz. 109, 839 (1996) [JETP 82, 451 (1996)].

    Google Scholar 

  5. F. P. Buff, J. Chem. Phys. 23, 419 (1955).

    Google Scholar 

  6. A. Dillman and G. E. A. Meier, J. Chem. Phys. 94, 3872 (1991).

    ADS  Google Scholar 

  7. I. J. Ford, A. Laaksonen, and M. Kulmala, J. Chem. Phys. 99, 764 (1993); V. I. Kalikman and M. E. H. van Dongen, J. Chem. Phys. 103, 4250 (1995).

    Article  ADS  Google Scholar 

  8. J. L. Katz, H. Saltsburg, and H. Reiss, J. Colloid Interface Sci. 21, 560 (1966).

    Google Scholar 

  9. M. R. Hoare and P. Pal, Adv. Phys. 24, 645 (1975).

    Article  ADS  Google Scholar 

  10. A. Yu. Grosberg and A. R. Khokhlov, Statistical Physics of Macromolecules, American Institute of Physics, New York (1994).

    Google Scholar 

  11. B. M. Smirnov, Usp. Fiz. Nauk 162, 97 (1992) [Sov. Phys. Usp. 35, 37 (1992)].

    Google Scholar 

  12. D. I. Zhukhovitskii, J. Chem. Phys. 101, 5076 (1994).

    Article  ADS  Google Scholar 

  13. H. J. C. Berendsen, J. P. M. Postma, W. F. van Gunsteren, A. DiNola, and J. R. Haak, J. Chem. Phys. 81, 3684 (1984).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Zh. Éksp. Teor. Fiz. 113, 181–190 (January 1998)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhukhovitskii, D.I. Structural transition in small gas-like clusters. J. Exp. Theor. Phys. 86, 101–106 (1998). https://doi.org/10.1134/1.558473

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/1.558473

Keywords

Navigation