Abstract
A mechanism and the corresponding mathematical model of the formation of the crystallization potential of water, based on protons and orientational defects, are considered. On the basis of the comparison with the known model based on impurity ions, it is shown that it is orientational defects that are responsible for the formation of the crystallization potential of diluted solutions at a crystallization rate of 10−5 m/s.
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References
E. G. Workman and S. E. Reynolds, Phys. Rev. 78, 254 (1950).
L. G. Kachurin and V. I. Bekryaev, Dokl. Akad. Nauk SSSR 130(1), 57 (1960) [Sov. Phys. Dokl. 5, 137 (1960)].
A. A. Shibkov, Yu. I. Golovin, M. A. Zheltov, et al., J. Cryst. Growth 236, 434 (2002).
Yu. I. Golovin, A. A. Shibkov, M. A. Zheltov, et al., Kondens. Sredy Mezhfaz. Granitsy 1(4), 304 (1999).
L. G. Kachurin, V. I. Bekryaev, and V. F. Psalomshchikov, Dokl. Akad. Nauk SSSR 174(5), 1122 (1967).
A. A. Mel’nikova, Kristallografiya 14(3), 548 (1969) [Sov. Phys. Crystallogr. 14, 464 (1969)].
B. L. Berri, I. O. Grigorov, L. G. Kachurin, et al., Problems of Engineering Glaciology (Nauka, Novosibirsk, 1986), p. 24 [in Russian].
L. G. Kachurin and N. O. Grigorov, Zh. Fiz. Khim. 51(7), 2864 (1977).
O. M. Rozental’ and F. E. Chetin, Multilayer Structural Ordering in Heterogeneous Processes of Ice Formation (Izd. Gos. Ped. Inst., Sverdlovsk, 1974) [in Russian].
A. A. Chernov and A. M. Mel’nikova, Kristallografiya 16(3), 477 (1971) [Sov. Phys. Crystallogr. 16, 404 (1971)].
A. A. Chernov and A. M. Mel’nikova, Kristallografiya 16(3), 488 (1971) [Sov. Phys. Crystallogr. 16, 413 (1971)].
L. G. Kachurin, Elektrokhimiya 6(9), 1294 (1970).
N. Maeno, The Science of Ice (Hokkaido Univ. Press, Sapporo, 1984; Mir, Moscow, 1988).
P. V. Hobbs, Ice Physics (Clarendon, Oxford, 1974).
A. V. Shavlov, Ice under Structural Transformations (Nauka, Novosibirsk, 1996) [in Russian].
A. V. Shavlov, Kriosfera Zemli 2(2), 58 (1998).
S. M. Ryvkin, Photoelectric Effects in Semiconductors (Fizmatlit, Moscow, 1963; Consultants Bureau, New York, 1964).
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Translated from Kristallografiya, Vol. 50, No. 6, 2005, pp. 1135–1140.
Original Russian Text Copyright © 2005 by Shavlov.
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Shavlov, A.V. A model of the separation of intrinsic charge carriers—Protons and orientational defects—at the crystallization front of water. Crystallogr. Rep. 50, 1055–1060 (2005). https://doi.org/10.1134/1.2132416
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DOI: https://doi.org/10.1134/1.2132416