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Vibrational spectra of 2-cyclooctylamino-5-nitropyridine and its mixtures with C60 and C70 fullerenes

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Abstract

The vibrational spectra of 2-cyclooctylamino-5-nitropyridine (COANP) solutions and the evolution of the spectra upon changing over from the solutions to solid-phase COANP are investigated. The bands observed in the spectra are assigned to the corresponding vibrational modes. The nature of the interaction of COANP with C60 and C70 fullerenes is elucidated by analyzing the transmission spectra of these compounds. No interaction of the COANP compound with C60 and C70 fullerenes is revealed under the studied conditions. It is assumed that the physical nature of this phenomenon can be associated with the formation of liquid-crystal clusters consisting of fullerene molecules.

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Translated from Fizika Tverdogo Tela, Vol. 47, No. 11, 2005, pp. 2097–2105.

Original Russian Text Copyright © 2005 by Leyderman, Radovanova, Sarkisov, Vikhnin.

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Leyderman, A., Radovanova, E.I., Sarkisov, S.S. et al. Vibrational spectra of 2-cyclooctylamino-5-nitropyridine and its mixtures with C60 and C70 fullerenes. Phys. Solid State 47, 2186–2195 (2005). https://doi.org/10.1134/1.2131166

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