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Phase transition with suppression of magnetism in BiFeO3 at high pressure

  • Condensed Matter
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Abstract

The magnetic behavior of a Bi57FeO3 powdered sample was studied at high pressures by the method of nuclear forward scattering (NFS) of synchrotron radiation. The NFS spectra from 57Fe nuclei were recorded at room temperature under high pressures up to 61.4 GPa, which were created in a diamond anvil cell. In the pressure interval 0 < P < 47 GPa, the magnetic hyperfine field H Fe at the 57Fe nuclei increased reaching a value of ∼52.5 T at 30 GPa, and then it slightly decreased to ∼49.6 T at P = 47 GPa. As the pressure was increased further, the field H Fe abruptly dropped to zero testifying a transition from the antiferromagnetic to a nonmagnetic state (magnetic collapse). In the pressure interval 47 < P < 61.4 GPa, the value of H Fe remained zero. The field H Fe recovered to the low-pressure values during decompression.

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From Pis’ma v Zhurnal Éksperimental’no\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) i Teoretichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) Fiziki, Vol. 82, No. 4, 2005, pp. 243–246.

Original English Text Copyright © 2005 by Gavriliuk, Struzhkin, Lyubutin, Hu, Mao.

The text was submitted by the authors in English.

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Gavriliuk, A.G., Struzhkin, V.V., Lyubutin, I.S. et al. Phase transition with suppression of magnetism in BiFeO3 at high pressure. Jetp Lett. 82, 224–227 (2005). https://doi.org/10.1134/1.2121819

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  • DOI: https://doi.org/10.1134/1.2121819

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