Abstract
The absorption spectrum of thin films of a new compound, K2CdI4, was studied. It was established that this compound belongs to direct-bandgap dielectrics and that its low-frequency electronic and excitonic excitations are localized in CdI 2−4 structural blocks of the crystal lattice. It was found that, in M 2CdI4 compounds (M = K, Rb, Cs), the bandgap width E g grows and the spin-orbit splitting of the valence band top decreases with increasing ionic radius of the alkali metal.
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Translated from Fizika Tverdogo Tela, Vol. 47, No. 3, 2005, pp. 460–462.
Original Russian Text Copyright © 2005 by Yunakova, Miloslavski\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \), Kovalenko.
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Yunakova, O.N., Miloslavskii, V.K. & Kovalenko, E.N. Absorption spectrum of thin K2CdI4 films. Phys. Solid State 47, 474–476 (2005). https://doi.org/10.1134/1.1884707
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DOI: https://doi.org/10.1134/1.1884707