Abstract
The phase diagram of methanol is studied by an ultrasonic technique over the temperature range 90–290 K at pressures up to 1.2 GPa. The pressure and temperature dependence of the velocity of longitudinal ultrasonic waves and the density of crystalline and liquid phases has been determined. Weak anomalies in the velocity of ultrasound in the liquid phase of methanol and the corresponding anomalous additional compression of the liquid at 230–250 K and 0.2–0.6 GPa have been found, and they are likely attributable to structural changes in the liquid phase.
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J. F. Mammone, S. K. Sharma, and M. Nicol, J. Phys. Chem. 84, 3130 (1980).
A. Arencibia, M. Taravillo, F. J. Perez, et al., Phys. Rev. Lett. 89, 195504 (2002).
E. M. Schulman, D. W. Dwyer, and D. C. Doetschman, J. Phys. Chem. 94, 7308 (1990).
S. L. Wallen, B. J. Palmer, B. C. Garrett, and C. R. Yonker, J. Phys. Chem. 100, 3959 (1996).
S. Bai and C. R. Yonker, J. Phys. Chem. 102, 8641 (1998).
P. W. Bridgman, Proc. Am. Acad. Arts Sci. 74, 399 (1942).
W. L. Jorgensen and M. Ibrahim, J. Am. Chem. Soc. 104, 373 (1982).
T. Yamaguchi, K. Hidaka, and F. K. Soper, Mol. Phys. 96, 1159 (1999).
P. A. Giguere and M. Pigeon-Gosselin, J. Solution Chem. 17, 1007 (1998).
D. W. Davidson, Can. J. Chem. 34, 124 (1956).
S. K. Garg and D. W. Davidson, J. Chem. Phys. 58, 189 (1973).
H. G. Carlson and E. F. Westrum, Jr., J. Chem. Phys. 54, 1464 (1971).
B. H. Torrie, O. S. Binbrek, M. Strauss, and I. P. Swainson, J. Solid State Chem. 166, 415 (2002).
A. H. Narten and A. Habenschuss, J. Phys. Chem. 80, 3387 (1984).
A. Wurflinger and R. Landau, J. Phys. Chem. Solids 38, 811 (1977).
D. R. Allan, S. J. Clark, M. J. P. Brugmans, et al., Phys. Rev. B 58, R11809 (1998).
T. F. Sun, J. A. Schouten, N. J. Trappeniers, and S. N. Biswas, Phys. Chem. 92, 652 (1988).
M. J. P. Brugmans and W. L. Vos, J. Phys. Chem. 103, 2661 (1995).
G. J. Piermarini, S. Block, and J. D. Barnett, J. Appl. Phys. 44, 5377 (1973).
J. M. Brown, L. J. Slutsky, K. A. Nelson, et al., Science 241, 65 (1988).
O. V. Stal’gorova, E. L. Gromnitskaya, D. R. Dmitriev, and F. F. Voronov, Prib. Tekh. Éksp. 39(6), 115 (1996) [Instrum. Exp. Tech. 39, 880 (1996)].
E. Yu. Tonkov, High Pressure Phase Transformations, A Handbook (Metallurgiya, Moscow, 1988; Gordon and Breach, Philadelphia, 1992), Vols. 1, 2.
G. H. Shaw, J. Chem. Phys. 84, 5862 (1986).
E. L. Gromnitskaya, O. V. Stal’gorova, A. G. Lyapin, et al., Pis’ma Zh. Éksp. Teor. Fiz. 78, 960 (2003) [JETP Lett. 78, 488 (2003)].
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Translated from Pis’ma v Zhurnal Éksperimental’no\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l}\) i Teoretichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l}\) Fiziki, Vol. 80, No. 9, 2004, pp. 697–702.
Original Russian Text Copyright © 2004 by Gromnitskaya, Stal’gorova, Yagafarov, Brazhkin, Lyapin, Popova.