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On one supramolecular mechanism of the nonlinear viscoelasticity of oriented polymers

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Abstract

A phenomenological model of the viscoelasticity of highly oriented polymer systems is developed based on the results of studying the relaxation of such systems (mainly, fibers of polyethylene terephthalate, polyamide-6, polyvinyl alcohol, and other polymers) in the loaded state. The effect of an applied load on their relaxation spectra agrees qualitatively with the deformation behavior of crystal-like bandles that are present in amorphous intercrystalline layers of the fibrillar supramolecular structure.

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Translated from Zhurnal Tekhnichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) Fiziki, Vol. 74, No. 11, 2004, pp. 58–62.

Original Russian Text Copyright © 2004 by Stalevich, Ginzburg.

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Stalevich, A.M., Ginzburg, B.M. On one supramolecular mechanism of the nonlinear viscoelasticity of oriented polymers. Tech. Phys. 49, 1452–1456 (2004). https://doi.org/10.1134/1.1826189

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