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Gibbs free energy and thermodynamic equilibrium boundary condition for a first-order phase transition in an isotropic solid

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Abstract

For elastic deformation of arbitrary magnitude in an isotropic solid, Legendre conjugate strain variables are found and used to define the Gibbs free energy of a deformable solid. An additional thermodynamic equilibrium condition is found in the case when transition in a nonuniform strain field is incomplete and there exists an equilibrium boundary between phases.

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Authors and Affiliations

  1. Vereshchagin Institute of High-Pressure Physics, Russian Academy of Sciences, Troitsk, Moscow oblast, 142432, Russia

    A. P. Kochkin

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  1. A. P. Kochkin
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Translated from Zhurnal Éksperimental’no\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l}\) i Teoretichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l}\) Fiziki, Vol. 126, No. 1, 2004, pp. 142–154.

Original Russian Text Copyright © 2004 by Kochkin.

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Kochkin, A.P. Gibbs free energy and thermodynamic equilibrium boundary condition for a first-order phase transition in an isotropic solid. J. Exp. Theor. Phys. 99, 121–132 (2004). https://doi.org/10.1134/1.1787085

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  • DOI: https://doi.org/10.1134/1.1787085

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