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Me 2O-P2O5-H2O solubility phase diagrams and growth of MeH2PO4 single crystals (Me = Li, Na, K, Rb, Cs, NH4)

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Abstract

The Me 2O-P2O5-H2O solubility phase diagrams are used to determine the optimum compositions and the temperatures for growing crystals of MeH2PO4 solid phases (Me = Li, Na, K, Rb, Cs, NH4). The optimum conditions for dynamic growth of dihydrophosphates of the elements of the first group and ammonium are determined. LiH2PO4, NaH2PO4, NaH2PO4 · 2H2O, NaH2PO4 · H2O, KH2PO4, K(H,D)2PO4, RbH2PO4, CsH2PO4, and (NH4)H2PO4 single crystals are grown on seed from aqueous solutions by the methods of temperature lowering and isothermal evaporation.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 119333, Russia

    L. V. Soboleva & A. E. Voloshin

Authors
  1. L. V. Soboleva
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  2. A. E. Voloshin
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Translated from Kristallografiya, Vol. 49, No. 4, 2004, pp. 773–777.

Original Russian Text Copyright © 2004 by Soboleva, Voloshin.

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Soboleva, L.V., Voloshin, A.E. Me 2O-P2O5-H2O solubility phase diagrams and growth of MeH2PO4 single crystals (Me = Li, Na, K, Rb, Cs, NH4). Crystallogr. Rep. 49, 693–697 (2004). https://doi.org/10.1134/1.1780638

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  • DOI: https://doi.org/10.1134/1.1780638

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