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Crystal and molecular structures of complex between ammonium iodide monohydrate and the cis-syn-cis isomer of dicyclohexano-18-crown-6

  • Structures of Organic Compounds
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Abstract

The structure of the [(DCH-6A ⋅ NH4)(H2O)I]2 complex obtained by the reaction between the cis-syn-cisisomer of dicyclohexano-18-crown-6 (DCH-6A) and NH4I has been determined by X-ray diffraction analysis. The crystals are triclinic, a = 9.314(3) Å, b = 11.951(2) Å, c = 12.040(1) Å, α = 77.36(1)°, β = 81.59(1)°, γ = 80.41(2)°, space group \(P\bar 1\), Z = 2, and the final R factor is 0.044. The structure is built up of the (DCH-6A ⋅ NH4) + cationic complexes, iodide anions, and water molecules. The ammonium ion forms three hydrogen bonds of the NH⋯O type [N⋯O, 2.881(5)–2.890(5) Å] with the oxygen atoms of the crown ether molecule. The organic cations are joined together into centrosymmetric dimers through the system of hydrogen bonds of the NH⋯OH type. The I−⋯O distances (where the O atom belongs to the bridging water molecule) fall in the range 3.558(4)–3.610(4) Å.

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Authors and Affiliations

  1. Institute of Applied Physics, Academy of Sciences of Moldova, Chisinau, Moldova

    M. S. Fonar’, V. Kh. Kravtsov & Yu. A. Simonov

  2. Physicochemical Institute for Human and Environmental Protection, Education Department, National Academy of Sciences of Ukraine, Odessa State University, Odessa, Ukraine

    É. V. Ganin

  3. Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland

    J. Lipkowski

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  1. M. S. Fonar’
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  2. V. Kh. Kravtsov
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  3. Yu. A. Simonov
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  4. É. V. Ganin
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  5. J. Lipkowski
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__________

Translated from Kristallografiya, Vol. 45, No. 1, 2000, pp. 77–83. p

Original Russian Text Copyright © 2000 by Fonar’, Kravtsov, Simonov, Ganin, Lipkowski.

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Fonar’, M.S., Kravtsov, V.K., Simonov, Y.A. et al. Crystal and molecular structures of complex between ammonium iodide monohydrate and the cis-syn-cis isomer of dicyclohexano-18-crown-6. Crystallogr. Rep. 45, 71–77 (2000). https://doi.org/10.1134/1.171139

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  • DOI: https://doi.org/10.1134/1.171139

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