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Effects of averaging of spin packets of interacting resonances in Gd3+ EPR spectra of scheelites

  • Semiconductors and Dielectrics
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Abstract

The EPR spectra of Gd3+ tetragonal centers in crystals with a scheelite structure are analyzed. It is found that the EPR spectra exhibit additional signals in the vicinity of coincidence of the resonance lines attributed to Gd3+ EPR transitions. It is shown that these signals are caused by averaging (due to relaxation spin-lattice transitions between the resonance doublets) of the internal part of the quasi-symmetric system of spin packets corresponding to the inhomogeneously broadened initial EPR lines. The quasi-symmetric arrangement of the spin packets is associated with the mosaic structure of the studied crystals.

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References

  1. V. A. Vazhenin and K. M. Starichenko, Pis’ma Zh. Éksp. Teor. Fiz. 51(8), 406 (1990) [JETP Lett. 51, 461 (1990)].

    Google Scholar 

  2. V. K. Voronkova, L. V. Mosina, Yu. V. Yablokov, et al., Mol. Phys. 75(6), 1275 (1992).

    Google Scholar 

  3. A. A. Galeev, N. M. Khasanova, A. V. Bykov, et al., Appl. Magn. Reson. 11, 61 (1996).

    Google Scholar 

  4. G. V. Mamin and V. N. Efimov, Mod. Phys. Lett. B 12(22), 929 (1998).

    ADS  Google Scholar 

  5. V. A. Vazhenin, K. M. Starichenko, and A. D. Gorlov, Fiz. Tverd. Tela (St. Petersburg) 35(9), 2450 (1993) [Phys. Solid State 35, 1214 (1993)].

    Google Scholar 

  6. V. A. Vazhenin, V. B. Guseva, and M. Yu. Artemov, Fiz. Tverd. Tela (St. Petersburg) 44(6), 1096 (2002) [Phys. Solid State 44, 1145 (2002)].

    Google Scholar 

  7. V. A. Vazhenin, V. B. Guseva, and M. Yu. Artemov, Fiz. Tverd. Tela (St. Petersburg) 45(1), 46 (2003) [Phys. Solid State 45, 46 (2003)].

    Google Scholar 

  8. M. L. Meil’man, Fiz. Tverd. Tela (Leningrad) 13(11), 3165 (1971) [Sov. Phys. Solid State 13, 2663 (1971)].

    Google Scholar 

  9. I. N. Kurkin, in Paramagnetic Resonance (Kazan. Gos. Univ., Kazan, 1969), No. 5, p. 31.

    Google Scholar 

  10. S. A. Altshuler and B. M. Kozyrev, Electron Paramagnetic Resonance in Compounds of Transition Elements (Nauka, Moscow, 1972; Halsted, New York, 1975).

    Google Scholar 

  11. V. A. Vazhenin and A. P. Potapov, Fiz. Tverd. Tela (Leningrad) 31(10), 304 (1989) [Sov. Phys. Solid State 31, 1831 (1989)].

    Google Scholar 

  12. N. G. Koloskova, in Paramagnetic Resonance (Kazan. Gos. Univ., Kazan, 1964), p. 115.

    Google Scholar 

  13. G. E. Barberis and R. Calvo, Solid State Commun. 12(10), 963 (1973).

    Article  Google Scholar 

  14. I. N. Geifman, in Radiospectroscopy of the Solid State (Naukova Dumka, Kiev, 1992), p. 417.

    Google Scholar 

  15. A. Abragam, The Principles of Nuclear Magnetism (Clarendon Press, Oxford, 1961; Inostrannaya Literatura, Moscow, 1963).

    Google Scholar 

  16. É. P. Zeer, V. E. Zobov, and O. V. Falaleev, New Effects in NMR of Polycrystals (Nauka, Novosibirsk, 1991).

    Google Scholar 

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Translated from Fizika Tverdogo Tela, Vol. 45, No. 12, 2003, pp. 2168–2172.

Original Russian Text Copyright © 2003 by Vazhenin, Guseva, Artemov.

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Vazhenin, V.A., Guseva, V.B. & Artemov, M.Y. Effects of averaging of spin packets of interacting resonances in Gd3+ EPR spectra of scheelites. Phys. Solid State 45, 2271–2275 (2003). https://doi.org/10.1134/1.1635496

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  • DOI: https://doi.org/10.1134/1.1635496

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