Abstract
The self-consistent field model is modified to take into account the effect of orientation correlations on the behavior of an electron solvated in a polar liquid. This model is used as the basis for calculating the maximum of the absorption spectrum as well as the temperature dependence of this maximum for an electron sol-vated in water and ammonium. The results are in accord with experimental data and with the results of calcu-lation by the quantum molecular dynamics method.
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Translated from Zhurnal Éksperimental’no\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) i Teoretichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) Fiziki, Vol. 124, No. 3, 2003, pp. 625–632.
Original Russian Text Copyright © 2003 by Chuev, Fedorov.
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Chuev, G.N., Fedorov, M.V. Modified model of self-consistent field for an electron solvated in a polar liquid. J. Exp. Theor. Phys. 97, 566–572 (2003). https://doi.org/10.1134/1.1618341
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DOI: https://doi.org/10.1134/1.1618341