Skip to main content
SpringerLink
Log in

Insertion of ethyl isothiocyanate into tungsten hexachloride: Crystal structure of ethyl-(4-ethyl-5-thioxo[1.2.4]dithiazolidin-3-ylidene)ammonium oxopentachlorotungstate(VI)

  • Structure of Organic Compounds
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

A product of the insertion of two isothiocyanate molecules into the same W-Cl bond, namely, W-Cl-WCl5{N(Et)C(S)N(Et)C(S)Cl} (I), is synthesized by the reaction of WCl6 with EtNCS in a dichloroethane solution. The hydrolysis of compound I results in the formation of single crystals of the complex

. The structure of crystals II is determined using X-ray diffraction. It is demonstrated that structural units of crystals II are the [WVIOCl5]− anionic complexes and the ethyl-(4-ethyl-5-thioxo[1.2.4]dithiazolidin-3-ylidene)ammonium cations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. C. Gibson, C. Redshaw, W. Clegg, et al., J. Chem. Soc., Chem. Commun., No. 22, 2635 (1994).

  2. N. A. Ovchinnikova, A. E. Sinyakov, A. M. Reznik, et al., Koord. Khim. 29 (2003) (in press).

  3. V. S. Sergienko, N. A. Ovchinnikova, G. G. Aleksandrov, et al., Zh. Neorg. Khim. 46(12), 1989 (2001).

    Google Scholar 

  4. G. M. Sheldrick, Acta Crystallogr., Sect. A: Found. Crystallogr. 46(5), 467 (1990).

    Google Scholar 

  5. G. M. Sheldrick, SHELXL93: Program for the Refinement of Crystal Structures (Univ. of Göttingen, Göttingen, 1993).

    Google Scholar 

  6. J. Houben, Die Methoden der organischen Chemie (George Thieme, Leipzig, 1924), Vol. 4, p. 36.

    Google Scholar 

  7. J. Beck and J. Walter, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 55(2), 260 (1999).

    Article  Google Scholar 

  8. J. M. Mayer, Inorg. Chem. 27(22), 3899 (1988).

    Article  Google Scholar 

  9. V. S. Sergienko, Russ. J. Inorg. Chem. 45, S37 (2000).

    Google Scholar 

  10. P. C. Junk and J. L. Atwood, J. Chem. Soc., Dalton Trans., No. 22, 4393 (1997).

  11. F. H. Allen, O. Kennard, D. G. Watson, et al., J. Chem. Soc., Dalton Trans., No. 1, S1 (1987).

  12. Yu. V. Zefirov and P. M. Zorkii, Zh. Strukt. Khim. 15(1), 118 (1974).

    Google Scholar 

  13. Yu. V. Zefirov and P. M. Zorkii, Zh. Strukt. Khim. 17(4), 745 (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    N. A. Ovchinnikova, A. E. Sinyakov, V. S. Sergienko & G. G. Aleksandrov

Authors
  1. N. A. Ovchinnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. E. Sinyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. S. Sergienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. G. Aleksandrov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Kristallografiya, Vol. 48, No. 4, 2003, pp. 653–656.

Original Russian Text Copyright © 2003 by Ovchinnikova, Sinyakov, Sergienko, Aleksandrov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ovchinnikova, N.A., Sinyakov, A.E., Sergienko, V.S. et al. Insertion of ethyl isothiocyanate into tungsten hexachloride: Crystal structure of ethyl-(4-ethyl-5-thioxo[1.2.4]dithiazolidin-3-ylidene)ammonium oxopentachlorotungstate(VI). Crystallogr. Rep. 48, 602–605 (2003). https://doi.org/10.1134/1.1595186

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/1.1595186

Keywords

Search

Navigation