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Scanning calorimetry measurements of the energy parameters of a plasmochemical polymer oxidation reaction

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Abstract

The contributions of heat fluxes of different nature to the total heat flux from a weakly ionized oxygen plasma of a low-pressure (20–120 Pa) RF discharge onto the calorimeter surface, on which a chemical reaction between atomic oxygen and a polymer proceeds, are distinguished. The activation energy (ΔE≈0.37 eV), the reaction heat (H≈27 kJ/g), and the rate constant for heat release in a surface plasmochemical reaction are determined.

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Authors and Affiliations

  1. Institute of General Physics, Russian Academy of Sciences, ul. Vavilova 38, Moscow, 117942, Russia

    A. N. Magunov

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  1. A. N. Magunov
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__________

Translated from Fizika Plazmy, Vol. 28, No. 4, 2002, pp. 392–400.

Original Russian Text Copyright © 2002 by Magunov.

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Magunov, A.N. Scanning calorimetry measurements of the energy parameters of a plasmochemical polymer oxidation reaction. Plasma Phys. Rep. 28, 359–366 (2002). https://doi.org/10.1134/1.1469177

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  • DOI: https://doi.org/10.1134/1.1469177

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