Abstract
The insulator-metal transitions of different kinds caused by heating above the melting temperature under pressure of tens kilobars and by compressing at the critical temperature to a pressure of about 1.1 kbar occur in liquid selenium. At tens kilobars, metallization is interpreted as the forbidden energy band vanishing due to a gradual structural transition (melting of polymer chains) described by the Clapeyron-Clausius equation. At supercritical temperatures, the insulator-metal transition is caused by percolation of overlapping electron shells (classically accessible spheres) of virtual atoms in molecules Se2 remaining when polymer chains decay. The percolation threshold in such a system has been found to increase due to coupling of virtual atoms. The thermally activated conductivity in the vicinity of percolation threshold has been calculated and compared with existing experimental data.
Similar content being viewed by others
References
R. Fischer and R. W. Schmutzler, in The Physics of Selenium and Tellurium, Ed. by E. Gerlach and P. Grosse (Springer-Verlag, Berlin, 1979), Springer Ser. Solid-State Sci. 13, 225 (1979).
N. F. Mott and E. A. Davis, Electron Processes in Non-crystalline Materials (Clarendon Press, Oxford, 1979; Mir, Moscow, 1992).
V. V. Brazhkin, R. N. Voloshin, and S. V. Popova, Pis’ma Zh. Éksp. Teor. Fiz. 50, 392 (1989) [JETP Lett. 50, 424 (1989)]; V. V. Brazhkin, private communication.
J. M. Ziman, Models of Disorder: the Theoretical Physics of Homogeneously Disordered Systems (Cambridge Univ. Press, Cambridge, 1979; Mir, Moscow, 1982).
N. F. Mott, Metal-Insulator Transition (Taylor & Francis, London, 1991).
P. A. Lee and T. V. Ramakrishnan, Rev. Mod. Phys. 57, 287 (1985).
M. J. Hirsch, Comments Condens. Matter Phys. 13, 249 (1987).
W. W. Warren, Jr. and R. Dupree, Phys. Rev. B 22, 2257 (1980).
S. Hosokawa, T. Kuboi, and K. Tamura, Ber. Bunsenges. Phys. Chem. 101, 120 (1997).
H. Hoshino, R. W. Schmutzler, and F. Hensel, Ber. Bunsenges. Phys. Chem. 80, 27 (1976).
H. Hoshino, R. W. Schmutzler, W. W. Warren, Jr., and F. Hensel, Philos. Mag. 33, 255 (1976).
W. W. Warren, Jr., J. Non-Cryst. Solids 250–252, 506 (1999).
S. Hosokawa and K. Tamura, J. Non-Cryst. Solids 205–207, 261 (1996).
F. Yonezawa, H. Ohtani, and T. Yamaguchi, J. Non-Cryst. Solids 250–252, 510 (1999).
F. Shimojo, K. Hoshino, M. Watabe, and Y. Zempo, J. Phys.: Condens. Matter 10, 1199 (1998).
F. Shimojo, K. Hoshino, Y. Zempo, and M. Watabe, J. Non-Cryst. Solids 250–252, 542 (1999).
A. A. Likal’ter, Usp. Fiz. Nauk 170, 831 (2000).
A. A. Likal’ter, Zh. Éksp. Teor. Fiz. 94(12), 157 (1988) [Sov. Phys. JETP 67, 2478 (1988)].
K.-P. Huber and G. Herzberg, Molecular Spectra and Molecular Structure (Van Nostrand, New York, 1979; Mir, Moscow, 1984).
B. I. Shklovskii and A. L. Efros, Electronic Properties of Doped Semiconductors (Nauka, Moscow, 1979; Springer-Verlag, New York, 1984).
N. F. Carnahan and K. E. Starling, J. Chem. Phys. 51, 635 (1969).
A. L. Bug, S. A. Safran, G. S. Grest, and I. Webman, Phys. Rev. Lett. 55, 1896 (1985).
D. Staufer and A. Aharony, Introduction to Percolation Theory (Taylor & Francis, Philadelphia, 1991, 2nd ed.).
A. A. Likal’ter, Zh. Éksp. Teor. Fiz. 107, 1996 (1995) [JETP 80, 1105 (1995)].
V. A. Alekseev, V. G. Ovcharenko, and Yu. F. Ryzhkov, J. Phys. (Paris) 41, C8–89 (1980); missed Figures, private communication by V. A. Alekseev.
A. A. Likalter, in Transport and Optical Properties of Nonideal Plasma, Ed. by G. A. Kobzev, I. T. Iakubov, and M. M. Popovich (Plenum, New York, 1995).
Author information
Authors and Affiliations
Additional information
__________
Translated from Zhurnal Éksperimental’no\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) i Teoretichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) Fiziki, Vol. 120, No. 2, 2001, pp. 379–388.
Original Russian Text Copyright © 2001 by Likalter.
Rights and permissions
About this article
Cite this article
Likalter, A.A. Structural transition and metallization in liquid selenium. J. Exp. Theor. Phys. 93, 336–343 (2001). https://doi.org/10.1134/1.1402734
Received:
Issue Date:
DOI: https://doi.org/10.1134/1.1402734