Abstract
The structural dissymmetry of crystals with coordinated groups of atoms performing some motion in the crystal is described in terms of the theory of hindered molecular motion based on the dynamic principles of invariance for the extended angular jump model. The spontaneous break of the symmetry in the ordered ammonium chloride phase is discussed with the invocation of the proton-relaxation data.
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References
A. Abragam, The Principles of Nuclear Magnetism (Clarendon Press, Oxford, 1961; Inostrannaya Literatura, Moscow, 1963).
K. A. Valiev and L. D. Éskin, Opt. Spektrosk. 12, 758 (1962).
E. N. Ivanov, Zh. Éksp. Teor. Fiz. 45, 1509 (1963) [Sov. Phys. JETP 18, 1041 (1963)].
F. I. Bashirov, Yu. L. Popov, K. S. Saikin, and R. A. Dautov, Zh. Éksp. Teor. Fiz. 62(5), 1803 (1972) [Sov. Phys. JETP 35, 937 (1972)].
P. Rigny, Physica (Amsterdam) 59, 707 (1972).
E. N. Ivanov, J. Stat. Phys. 8(2), 177 (1973).
M. Bée, Mol. Phys. 47, 83 (1982).
F. I. Bashirov, Proceedings of the XXVII Ampére Congress on Magnetic Resonance and Related Phenomena, Kazan, 1994, Vol. 1, p. 282.
K. Tomita, Phys. Rev. 89(2), 429 (1953).
L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics, Vol. 3: Quantum Mechanics: Non-Relativistic Theory (Fizmatgiz, Moscow, 1963; Pergamon, New York, 1977).
Introductory Essays Presented as Lectures at the 4th Waterloo International Summer School on Nuclear Magnetic Resonance, Univ. of Waterloo, 1975, Ed. by M. M. Pintar (Springer-Verlag, Berlin, 1976), MNR 13, 125 (1976).
R. S. Knox and A. Gold, Symmetry in the Solid State (Benjamin, New York, 1964; Nauka, Moscow, 1970).
J. F. Nye, Physical Properties of Crystals: Their Representation by Tensors and Matrices (Clarendon Press, Oxford, 1964; Mir, Moscow, 1967).
E. P. Wigner, Phys. Today 17, 34 (1964) [Usp. Fiz. Nauk 83, 729 (1964)].
P. Debye, Polar Molecules (Chemical Catalog Co., New York, 1929; Gostekhizdat, Moscow, 1934).
Ya. I. Frenkel, Kinetic Theory of Liquids (Akad. Nauk SSSR, Moscow, 1959), Vol. 3.
A. M. Leushin, Tables of Functions Transformed by Irreducible Representations of Crystallographic Point Groups (Nauka, Moscow, 1968).
F. I. Bashirov, Eur. Phys. J.: Appl. Phys. 8, 99 (1999).
F. I. Bashirov, Mol. Phys. 91, 281 (1997).
F. I. Bashirov and N. K. Gaisin, J. Raman Spectrosc. 29, 131 (1998).
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Translated from Kristallografiya, Vol. 46, No. 3, 2001, pp. 494–499.
Original Russian Text Copyright © 2001 by Bashirov.
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Bashirov, F.I. Spontaneous break of symmetry in molecular crystals. Crystallogr. Rep. 46, 444–449 (2001). https://doi.org/10.1134/1.1376475
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DOI: https://doi.org/10.1134/1.1376475