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Synthesis and crystal structure of bis(carbamide)chromatoneptunyl NpO2CrO4 · 2[OC(NH2)2]

  • Structure of Coordination Compounds
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Abstract

The crystal structure of the hexavalent neptunium complex NpO2CrO4 · 2[OC(NH2)2] is determined. The crystal data are a = 7.192(2) Å, b = 12.902(4) Å, c = 11.226(3) Å, β = 92.19(2)°, V = 1040.9(4) Å3, space group P21/n, Z = 4, d calcd = 3.223 g/cm3, R = 0.045, and R w = 0.130. The coordination polyhedron of the Np atom is the pentagonal bipyramid whose equatorial plane is formed by the oxygen atoms of the chromate ions and carbamide molecules.

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References

  1. Yu. N. Mikhailov, Yu. E. Gorbunova, E. A. Demchenko, et al., Zh. Neorg. Khim. 43(11), 1831 (1988).

    Google Scholar 

  2. V. N. Serezhkin and V. K. Trunov, Kristallografiya 26(2), 301 (1981) [Sov. Phys. Crystallogr. 26, 169 (1981)].

    Google Scholar 

  3. V. N. Serezhkin, M. A. Soldatkina, V. A. Efremov, and V. K. Trunov, Koord. Khim. 7, 629 (1981).

    Google Scholar 

  4. S. Swaminathan, B. M. Craven, and R. K. McMullan, Acta Crystallogr., Sect. B: Struct. Sci. B40, 300 (1984).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117915, Russia

    G. B. Andreev, A. M. Fedoseev & N. A. Budantseva

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russia

    M. Yu. Antipin

Authors
  1. G. B. Andreev
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  2. M. Yu. Antipin
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  3. A. M. Fedoseev
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  4. N. A. Budantseva
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Translated from Kristallografiya, Vol. 46, No. 3, 2001, pp. 433–434.

Original Russian Text Copyright © 2001 by Andreev, Antipin, Fedoseev, Budantseva.

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Andreev, G.B., Antipin, M.Y., Fedoseev, A.M. et al. Synthesis and crystal structure of bis(carbamide)chromatoneptunyl NpO2CrO4 · 2[OC(NH2)2]. Crystallogr. Rep. 46, 383–384 (2001). https://doi.org/10.1134/1.1376464

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  • DOI: https://doi.org/10.1134/1.1376464

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