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Crystal structure of BaNb0.9S3

  • Structure of Inorganic Compounds
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Abstract

Single crystals of the composition BaNb0.9S3 have been synthesized from the BaS, Nb, and S mixture and the BaCl2 flux at 900°C. The BaNb0.9S3 structure was refined by X-ray single-crystal and electron diffraction data. The compound is crystallized in the sp. gr. P63/mmc (z = 2) with the unit-cell parameters a = 6.839(1) Å and c = 5.745(1) Å. It was established that the cationic vacancies in the niobium positions are statistically distributed over the structure.

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References

  1. R. A. Gardner, M. Vlasse, and A. Wold, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B25, 781 (1969).

    Google Scholar 

  2. R. A. Gardner, M. Vlasse, and A. Wold, Inorg. Chem. 8, 2784 (1969).

    Google Scholar 

  3. P. C. Donohue and J. F. Weiher, J. Solid State Chem. 10, 142 (1974).

    Article  ADS  Google Scholar 

  4. J. Yan, K. V. Ramanujachary, and M. Greenblatt, Mater. Res. Bull. 30, 463 (1995).

    Article  Google Scholar 

  5. S.-J. Kim, H.-S. Bae, K.-A. Yee, et al., J. Solid State Chem. 115, 427 (1995).

    Article  Google Scholar 

  6. N. Kiijima, K. Morie, S. Chikazawa, et al., J. Solid State Chem. 142, 57 (1999).

    ADS  Google Scholar 

  7. L. G. Akselrud, Yu. N. Gryn, P. Yu. Zavalij, et al., CSD. Thes. Report on 12th ESM, Moscow, 1989, Vol. 3, p. 155.

  8. Y. Takeda, F. Kanamaru, M. Shimada, and M. Koizumi, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. B32, 2464 (1976).

    Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, Moscow State University, Vorob’evy gory, Moscow, 119899, Russia

    A. Yu. Grippa, O. G. D’yachenko, A. M. Abakumov & E. V. Antipov

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  1. A. Yu. Grippa
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  2. O. G. D’yachenko
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  3. A. M. Abakumov
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  4. E. V. Antipov
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Translated from Kristallografiya, Vol. 46, No. 3, 2001, pp. 423–426.

Original Russian Text Copyright © 2001 by Grippa, D’yachenko, Abakumov, Antipov.

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Grippa, A.Y., D’yachenko, O.G., Abakumov, A.M. et al. Crystal structure of BaNb0.9S3 . Crystallogr. Rep. 46, 373–376 (2001). https://doi.org/10.1134/1.1376462

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  • DOI: https://doi.org/10.1134/1.1376462

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