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Crystal structure of zinc iodide complex with carbamide, ZnI2 · 2CO(NH2)2

  • Structure of Coordination Compounds
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Abstract

The structure of ZnI2 · 2CO(NH2)2 is determined by single-crystal X-ray diffraction. The crystals are monoclinic, a = 12.694(3) Å, b = 6.886(2) Å, c = 13.161(3) Å, β = 110.58(2)°, Z = 4, space group P21/a, and R = 0.0337 for 2481 reflections. Similar to the chloride analogue, the structure consists of discrete molecules with tetrahedrally coordinated Zn atoms. The bond lengths and angles are as follows: Zn-I, 2.5749(8) and 2.5473(8) Å; Zn-O, 1.954(3) and 1.985(4) Å; IZnI, 113.74(3)°; OZnO, 100.5(2)°; and IZnO, 108.5°–113.1(1)°. The crystal structure agrees with the IR and electronic absorption spectra of the crystals.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333, Russia

    N. G. Furmanova

  2. Institute of Chemistry and Chemical Technology, National Academy of Sciences of Kyrgyzstan, Bishkek, 720071, Kyrgyzstan

    V. F. Resnyanskii, K. S. Sulaimankulov, Sh. Zh. Zhorobekova & D. K. Sulaimankulova

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  1. N. G. Furmanova
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  2. V. F. Resnyanskii
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  3. K. S. Sulaimankulov
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  4. Sh. Zh. Zhorobekova
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  5. D. K. Sulaimankulova
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__________

Translated from Kristallografiya, Vol. 46, No. 1, 2001, pp. 58–62.

Original Russian Text Copyright © 2001 by Furmanova, Resnyanski\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \), Sulavmankulov, Zhorobekova, Sula\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \)mankulova.

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Furmanova, N.G., Resnyanskii, V.F., Sulaimankulov, K.S. et al. Crystal structure of zinc iodide complex with carbamide, ZnI2 · 2CO(NH2)2 . Crystallogr. Rep. 46, 51–55 (2001). https://doi.org/10.1134/1.1343126

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  • DOI: https://doi.org/10.1134/1.1343126

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