Abstract
The temperature dependences of the conductivity and the thermoelectric coefficient in TlFeS2 and TlFeSe2 samples have been investigated in the temperature range 85–400 K. The variable-range hopping conduction has been established. It is found that the density of localized states N F near the Fermi level is 1.7×1018 and 3.3×1018 eV−1 cm−3, and the average hopping length R is 109 and 104 Å for TlFeS2 and TlFeSe2, respectively. The non-Arrhenius (activationless) behavior of the hopping conductivity is established in the temperature region T<200 K for TlFeS2 and T<250 K for TlFeSe2.
Similar content being viewed by others
References
A. Kutoglu, Naturwissenchaften B 61(3), 125 (1974).
K. Klepp and H. Boller, Monatsh. Chem. B 110(5), 1045 (1979).
É. M. Kerimova, F. M. Seidov, S. N. Mustafaeva, and S. S. Abdinbekov, Neorg. Mater. 35(2), 157 (1999).
N. F. Mott and E. A. Davis, Electronic Processes in Non-Crystalline Materials (Oxford Univ. Press, Oxford, 1971; Mir, Moscow, 1974).
V. Augelli, C. Manfredotti, R. Murri, et al., Nuovo Cimento 38(2), 327 (1977).
B. I. Shklovskii, Fiz. Tekh. Poluprovodn. (Leningrad) 6(12), 2335 (1972) [Sov. Phys. Semicond. 6, 1964 (1972)].
S. N. Mustafaeva, Neorg. Mater. 30(5), 619 (1994).
Author information
Authors and Affiliations
Additional information
__________
Translated from Fizika Tverdogo Tela, Vol. 42, No. 12, 2000, pp. 2132–2135.
Original Russian Text Copyright © 2000 by Mustafaeva, Kerimova, Dzhabbarly.
Rights and permissions
About this article
Cite this article
Mustafaeva, S.N., Kerimova, É.M. & Dzhabbarly, A.I. Charge transfer in TlFeS2 and TlFeSe2 . Phys. Solid State 42, 2197–2199 (2000). https://doi.org/10.1134/1.1332139
Received:
Issue Date:
DOI: https://doi.org/10.1134/1.1332139