Abstract
The current-voltage characteristics of organic compounds at a tip platinum emitter have been studied in 0.2-1.0 V/Å fields. It is shown that the parameter (V-ϕ) does not affect the formation of the desorption ion barrier in the field ionization of atoms and molecules under a high potential gradient providing electron tunneling to the Fermi level of the emitter material and, therefore, the probability of the ion desorption cannot explicitly depend on this parameter.
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References
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H. D. Beckey, Principles of Field Ionization and Field-Desorption Mass Spectrometry (Pergamon Press, Oxford, 1972), p. 325.
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Translated from Zhurnal Tekhnichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) Fiziki, Vol. 70, No. 1, 2000, pp. 79–84.
Original Russian Text Copyright © 2000 by Grishin.
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Grishin, N.N. Mechanism of ionization of organic compounds on tip emitters. Tech. Phys. 45, 77–83 (2000). https://doi.org/10.1134/1.1259574
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DOI: https://doi.org/10.1134/1.1259574