Skip to main content
Log in

Choice of conditions of an electrical discharge for generating chemically active particles for the decomposition of impurities in water

  • Gas Discharges, Plasmas
  • Published:
Technical Physics Aims and scope Submit manuscript

Abstract

An electrical discharge between a liquid surface and an electrode positioned above it is considered. A second electrode, which delivers the output from a high-voltage source, is located at the bottom of the vessel containing the liquid. The conditions that must be met by the electrical discharge in order to efficiently initiate reactions in the liquid phase are analyzed. Under these conditions the number of active particles generated by the discharge turns out to depend on the concentration in the liquid of the substance with which the active particles interact. It is shown that for a corona or spark discharge the reactions can occur in a liquid layer 10–20 mm thick and that for specific reactions there exists an optimum value of the electric field at which the energy expenditures on the initiation of the reaction will be minimum.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. N. Andreev, Organic Synthesis in Electrical Discharges [in Russian], edited by. A. D. Petrov, Izd. AN SSSR, Moscow-Leningrad (1953), 334 pp.

    Google Scholar 

  2. K. S. Klopovskii, A. S. Kovalev, D. V. Lopaev et al., Fiz. Plazmy 18, 1606 (1992) [Sov. J. Plasma Phys. 18, 834 (1992)].

    Google Scholar 

  3. N. G. Basov, V. A. Danilychev, V. I. Panteleev et al., Dokl. Akad. Nauk SSSR 233, 839 (1977) [Sov. Phys. Dokl. 22, 213 (1977)].

    Google Scholar 

  4. I. P. Vereshchagin, Corona Discharge in Electron-Ion Technology [in Russian], Énergoatomizdat, Moscow (1985), 160 pp.

    Google Scholar 

  5. Yu. S. Akishev, A. A. Deryugin, I. V. Kochetov et al., Fiz. Plazmy 20, 585 (1994).

    Google Scholar 

  6. A. P. Shvedchikov, É. V. Belousova, A. V. Polyakova et al., Khim. Vysokikh Énergii 26, 317 (1992).

    Google Scholar 

  7. A. Hickling, in Modern Aspects of Electrochemistry, No. 6, Butterworths, London (1971), 329 pp.

    Google Scholar 

  8. V. I. Pavlov, Dokl. Akad. Nauk 55, 37 (1947).

    Google Scholar 

  9. A. P. Shvedchikov, É. V. Belousova, A. V. Polyakova et al., Khim. Vysokikh Énergii 27, 63 (1993).

    Google Scholar 

  10. V. F. Kozhinov and I. V. Kozhinov, in Ozonation of Water [in Russian], Stroiidat, Moscow (1974), p. 21.

    Google Scholar 

  11. J. Hoigne, in Process Technology for Water Treatment, edited by S. Stucki, Plenum, New York (1988), p. 121.

    Google Scholar 

  12. Yu. A. Kulagin, L. A. Shelepin, and V. N. Yaryga, Tr. Fiz. Inst. Akad. Nauk 218, 166 (1994).

    Google Scholar 

  13. I. M. Piskarev and A. I. Sevast’yanov, Abstracts of the Sixth International Frumkinsk Symposium “Fundamental Aspects of Electrochemistry” [in Russian], MGU, Moscow (1995), p. 138.

    Google Scholar 

  14. I. M. Piskarev, A. E. Rylova, and A. I. Sevast’yanov, Elektrokhimiya 32, 895 (1996).

    Google Scholar 

  15. I. M. Piskarev and A. I. Sevast’yanov, Second International Congress EKVATEK-96, Moscow (1996), p. 364.

  16. V. V. Skorcheletti, Theoretical Electrochemistry, Gos. Nauchno-Tekh. Izd. Khim. Lit., Leningrad (1959), 87 pp.

    Google Scholar 

  17. Yu. P. Raizer, Gas Discharge Physics [Springer, New York (1997) Nauka, Moscow (1992), 438 pp.].

    Google Scholar 

  18. Yu. S. Akishev, A. A. Deryugin, I. V. Karal’nik et al., Fiz. Plazmy 20, 571 (1994).

    Google Scholar 

  19. I. M. Piskarev, A. E. Rylova, and A. I. Sevast’yanov, NIIYaF MGU Preprint No. 94-13/335 [in Russian], Scientific-Research Institute of Nuclear Physics, Moscow State University, Moscow (1994).

Download references

Author information

Authors and Affiliations

Authors

Additional information

Zh. Tekh. Fiz. 69, 58–63 (January 1999)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Piskarev, I.M. Choice of conditions of an electrical discharge for generating chemically active particles for the decomposition of impurities in water. Tech. Phys. 44, 53–58 (1999). https://doi.org/10.1134/1.1259251

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/1.1259251

Keywords

Navigation