Abstract
A universal derivation of the thermodynamic equations on the basis of a combined analysis of the exact relations for any material — the virial theorem, the shock adiabat, and the differential thermodynamic identity relating the thermic and caloric equations of state of matter — is given. This combination makes it possible to reduce the fundamental problem of thermodynamics to a boundary-value problem of mathematical physics. Analytic relations T s=T(P s,ρ s and T s=T(D,u) are obtained for classical systems.
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Zh. Tekh. Fiz. 68, 1–9 (October 1998)
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Sarry, M.F. Thermodynamic theory of the equation of state of materials. Tech. Phys. 43, 1137–1144 (1998). https://doi.org/10.1134/1.1259168
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DOI: https://doi.org/10.1134/1.1259168