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Properties of diamondlike films obtained in a barrier discharge at atmospheric pressure

  • Surfaces, Electron and Ion Emission
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Abstract

Diamondlike films are synthesized from gaseous hydrocarbons in a barrier discharge at atmospheric pressure. The films were investigated using transmission electron microscopy, electron diffraction, and infrared spectroscopy. A technique for determining the quantitative characteristics of the films (hydrogen content, ratio of different types of carbon-carbon bonds and hydrocarbon groups) using standard samples is described. The highest-quality films were obtained from methane (ratio of hydrogen to carbon atoms H/C=1.04, fraction of diamondlike to graphitelike bonds sp 3: sp 2=100%: 0%) and from a mixture of acetylene and hydrogen in the ratio 1:19 (H/C=0.73, sp 3: sp 2=68%: 32%).

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References

  1. S. Aisenberg, J. Vac. Sci. Technol. A 8, 2150 (1990).

    Article  ADS  Google Scholar 

  2. S. Aisenberg and R. Chabot, J. Appl. Phys. 42, 2953 (1971).

    Article  Google Scholar 

  3. E. G. Spencer, P. H. Schmidt, D. C. Joy, and F. J. Sansalone, Appl. Phys. Lett. 29, 118 (1976).

    Article  ADS  Google Scholar 

  4. Z. Zhiao, Vacuum 40(6), 505 (1990).

    Google Scholar 

  5. W. Moller, in Proceedings of the Third TATF, Strasbourg, France, 1991, p. 273.

  6. T. G. Owano and C. H. Kruger, Plasma Chem. Plasma Process. 13(3), 433 (1993).

    Article  Google Scholar 

  7. S. K. Baldwin and T. G. Owano, Appl. Phys. Lett. 67, 194 (1995).

    Article  ADS  Google Scholar 

  8. D. B. Oakes and J. E. Butler, J. Appl. Phys. 69, 2602 (1991).

    Article  ADS  Google Scholar 

  9. R. Schwarz and J. Salge, in Proceedings of ISPC 11, Loughborough, England, 1993, p. 1071.

  10. V. Gibalov and D. Braun, in Proceedings of ISPC 10, Bochum, Germany, 1991, Vol. 3.2, pp. 7.1–7.6.

  11. S. Kumar, Appl. Phys. Lett. 58, 1836 (1991).

    ADS  Google Scholar 

  12. V. V. Sleptsov, V. M. Elinson, and G. F. Ivanovskii, Vak. Tekh. Tekhnol. 2, No. 4, 69 (1992).

    Google Scholar 

  13. J. J. Cuomo and J. P. Doyle, Appl. Phys. Lett. 58, 466 (1991).

    Article  ADS  Google Scholar 

  14. L. J. Bellamy, The Infra-Red Spectra of Complex Molecules, 2nd ed. (Barnes and Noble, New York, 1958).

    Google Scholar 

  15. M. Cardona, Phys. Status Solidi B 118, 463 (1983).

    Google Scholar 

  16. J. W. Zou, K. Schmidt, K. Reichelt, and B. Dischler, J. Appl. Phys. 68, 1237 (1990).

    Article  Google Scholar 

  17. É. F. Chaikovskii, V. M. Puzikov, and A. V. Semenov, Arkh. Nauki Mater. 7(2), 187 (1986).

    Google Scholar 

  18. B. Dischler and E. Bayer, J. Appl. Phys. 68, 1237 (1990).

    Article  ADS  Google Scholar 

  19. D. G. Goodwin, J. Appl. Phys. 74, 6888 (1993).

    ADS  Google Scholar 

  20. Yu. A. Mankelevich, A. T. Rakhimov, and N. V. Suetin, Fiz. Plazmy 21, 921 (1995) [Plasma Phys. Rep. 21, 872 (1995)].

    Google Scholar 

  21. X. Jiang and K. Reichelt, J. Appl. Phys. 68, 1018 (1990).

    ADS  Google Scholar 

  22. P. Catania and Y. Sampeur, in Proceedings of CIP 93, Antibes, France, 1993, p. 116.

  23. M. Ham and K. Lou, J. Vac. Sci. Technol. A 8, 2149 (1990).

    Article  Google Scholar 

  24. A. Buuron and D. Schram, in Proceedings of CIP 93, Antibes, France, 1993, p. 89.

  25. B. V. Deryagin and D. V. Fedoseev, Growth of Diamond and Graphite from the Gas Phase [in Russian], Nauka, Moscow (1977).

    Google Scholar 

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Zh. Tekh. Fiz. 67, 100–104 (August 1997)

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Bugaev, S.P., Korotaev, A.D., Oskomov, K.V. et al. Properties of diamondlike films obtained in a barrier discharge at atmospheric pressure. Tech. Phys. 42, 945–949 (1997). https://doi.org/10.1134/1.1258759

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  • DOI: https://doi.org/10.1134/1.1258759

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