Abstract
The temperature dependence of the spin-lattice relaxation time T 1 and the 7Li NMR spectra of the Li0.7Nb3Se4 intercalation compound with one-dimensional channel structure have been studied. It is found that the temperature dependence of T 1 exhibits two relaxation minima, and the quadrupole splitting in the Li NMR spectra shows an anomalous temperature behavior. The inference is drawn that the observed effects are associated with the high-rate diffusive motion of lithium ions along one-dimensional channels and the interchannel transitions.
Similar content being viewed by others
References
V. E. Fedorov, Chalcogenides of High-Melting Transition Metals: Quasi-One-Dimensional Compounds (Nauka, Novosibirsk, 1988).
V. L. Pokrovskii and A. L. Talapov, Zh. Éksp. Teor. Fiz. 75(3), 1151 (1978).
Yu. G. Kriger, S. G. Kozlova, S. P. Gabuda, et al., Fiz. Tverd. Tela (Leningrad) 27(10), 3121 (1985).
Yu. Kriger, G. V. Sikorskaya, and V. E. Fedorov, Zh. Fiz. Khim. 34(6), 135 (1993).
S. Basu and W. L. Worrell, Fast Ion Transport in Solids (New York, 1979).
V. M. Buznik, Nuclear Resonance in Ionic Crystals (Nauka, Novosibirsk, 1981).
K. Selte and A. Kjekshus, Acta Crystallogr. 17(2), 248 (1964).
Ch. Slicter, Principles of Magnetic Resonance (Springer-Verlag, Heidelberg, 1978; Mir, Moscow, 1981).
V. S. Grechishkin, Nuclear Quadrupole Interactions in Solids (Nauka, Moscow, 1973).
Author information
Authors and Affiliations
Additional information
__________
Translated from Fizika Tverdogo Tela, Vol. 42, No. 2, 2000, pp. 251–253.
Original Russian Text Copyright © 2000 by Kriger, Mishchenko, Semenov, Tkachev, Fedorov.
Rights and permissions
About this article
Cite this article
Kriger, Y.G., Mishchenko, A.V., Semenov, A.R. et al. 7Li NMR study of the mobility of lithium ions in one-dimensional channels of Nb3Se4 . Phys. Solid State 42, 257–260 (2000). https://doi.org/10.1134/1.1131156
Received:
Issue Date:
DOI: https://doi.org/10.1134/1.1131156