Abstract
First studies of the structure of the valence region in the conversion spectrum of the 1.56-keV (M1+E2) transition in 201Hg have been carried out. Physicochemical environment has been found to affect substantially the local electron density of impurity mercury atoms. The mechanisms responsible for the electronic-structure rearrangement are discussed.
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V. N. Gerasimov and V. M. Kulakov, Izv. Akad. Nauk SSSR, Ser. Fiz 54, 1705 (1990).
I. M. Band, L. A. Sliv, and M. B. Trzhaskovskaya, Nucl. Phys. A 156, 170 (1970).
D. P. Grechukhin and A. A. Soldatov, Vopr. At. Nauki Tekh., Ser.: Yad. Konstanty 2(56), 36 (1984).
V. N. Gerasimov and V. M. Kulakov, Effect of Chemical Environment on the Conversion Process. Conversion Electron Spectroscopy of Technetium Compounds: a Review [in Russian], TsNII atominf., Moscow (1988), 71 pp.
V. N. Gerasimov, A. G. Zelenkov, V. M. Kulakov, V. A. Pchelin, M. V. Sokolovskaya, A. A. Soldatov, and L. V. Chistyakov, Zh. Éksp. Teor. Fiz. 82, 362 (1982) [Sov. Phys. JETP 55, 205 (1982)].
V. N. Gerasimov, A. G. Zelenkov, V. M. Kulakov, and A. A. Soldatov, Zh. Éksp. Teor. Fiz. 89, 540 (1985) [Sov. Phys. JETP 62, 307 (1985)].
V. I. Zhudov, A. G. Zelenkov, V. M. Kulakov, B. V. Odinov, and Yu. A. Teterin, in Abstracts of the XXX All-Union Meeting on Nuclear Spectroscopy and Nuclear Structure (Leningrad, 1980), p. 614.
D. P. Grechukhin, V. I. Zhudov, A. G. Zelenkov, V. M. Kulakov, B. V. Odinov, A. A. Soldatov, and Yu. A. Teterin, JETP Lett. 31, 592 (1980).
V. I. Zhudov, V. M. Kulakov, and A. D. Panov, Vopr. At. Nauki Tekh., Ser.: Yad. Konstanty 3(36), 48 (1986).
A. D. Panov and V. M. Kulakov, Study of the Electronic Structure of Uranium Compounds by Conversion Spectroscopy: Review [in Russian], TsNII atominform. (Moscow, 1988), 45 pp.
J. W. Petersen, G. Weyer, E. Holzschuh, W. Kundig, and ISOLDE Collaboration, Phys. Lett. A 146, 226 (1990).
Tables of Isotopes, edited by C. M. Lederer and V. S. Shirley, Wiley, New York (1978), pp. 1291–1292.
O. Dragoun, V. Brabes, M. Ryšavý, A. Špalek, and K. Freitag, Z. Phys. A 326, 279 (1987).
V. N. Gerasimov, D. V. Grebennikov, V. M. Kulakov, S. K. Lisin, and V. V. Kharitonov, Yadernaya Fizika 60, 1948 (1997).
M. A. Kelly and C. E. Tyler, Hewlett-Packard J. 24, No. 11, 2 (1973).
A. Savitzky and M. J. E. Golay, Anal. Chem. 36, 1627 (1964).
J. Steinier, Y. Termonia, and J. Deltour, Anal. Chem. 44, 1906 (1972).
A. D. Panov, IAÉ Preprint No. 6019/15 (Moscow, 1997), 31 pp.
Yu. A. Teterin and S. G. Gagarin, Usp. Khim. 65, 895 (1996).
I. M. Band and M. B. Trzhaskovskaya, Izv. Akad. Nauk SSSR, Ser. Fiz 55, 2121 (1991).
S. C. Keeton and T. L. Loucks, Phys. Rev. 152, 548 (1966).
S. Svensson, N. Mårtensson, E. Basilier, P. Å. Malmqvist, U. Gelius, and K. Siegbahn, J. Electron Spectrosc. Relat. Phenom. 9, 51 (1976).
J. C. Fuggle and N. Mårtensson, J. Electron Spectrosc. Relat. Phenom. 21, 275 (1980).
A. S. Koster and H. Mendel, J. Phys. Chem. Solids 31, 2511 (1970).
V. V. Nemoshkalenko and V. G. Aleshin, in Electron Spectroscopy of Crystals (Naukova Dumka, Kiev, 1976), pp. 222–225.
K. S. Krasnov, in Molecular Constants of Inorganic Compounds: Handbook [in Russian], Khimiya, Leningrad (1979), p. 96.
D. V. Grebennikov, V. I. Zhudov, V. M. Kulakov, B. V. Odinov, and A. D. Panov, Vopr. At. Nauki Tekh., Ser.: Yad. Konstanty 5(13), 68 (1990).
C. Schober, N. E. Christensen, and P. Ziesche, Solid State Commun. 77, 173 (1991).
V. N. Gerasimov, A. G. Zelenkov, V. M. Kulakov, V. A. Pchelin, M. V. Sokolovskaya, A. A. Soldatov, and L. V. Chistyakov, Zh. Éksp. Teor. Fiz. 86, 1169 (1984) [Sov. Phys. JETP 59, 683 (1984)].
E. Hartmann, R. Der, and M. Nagel, Z. Phys. A 290, 349 (1979).
E. Hartmann and G. Seifert, Phys. Status Solidi B 100, 589 (1980).
T. Ziegler, A. Rauk, and E. J. Baerends, Chem. Phys. 16, 209 (1976).
V. N. Gerasimov, V. Yu. Dobretsov, V. M. Kulakov, and A. A. Soldatov, Izv. RAN, Ser. Fiz. 56, No. 7, 181 (1992).
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Fiz. Tverd. Tela (St. Petersburg) 40, 1610–1614 (September 1998)
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Kharitonov, V.V., Gerasimov, V.N. Study of the electronic structure of impurity mercury atoms in compounds by conversion-electron spectroscopy. Phys. Solid State 40, 1462–1466 (1998). https://doi.org/10.1134/1.1130615
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DOI: https://doi.org/10.1134/1.1130615