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On Possible Reasons for the Relationship of Zero-Charge Potentials and Critical Passivation Potentials of IV–VI and VIII Group Transition Metals of Periodic System in Neutral Organic Media

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Abstract

Electrostatic nature of the relationship of zero-charge potentials and critical passivation potentials of IV –VI and VIII group transition metals of the periodic system in a series of proton donor and aprotic solvents, whose adsorption on the metal surface initiates transition of metal to passive state at a particular shift of potential relative to Eq = 0, is considered.

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Correspondence to A. A. Popova.

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Translated by A. Muravev

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Popova, A.A., Bedanokov, R.A. On Possible Reasons for the Relationship of Zero-Charge Potentials and Critical Passivation Potentials of IV–VI and VIII Group Transition Metals of Periodic System in Neutral Organic Media. Prot Met Phys Chem Surf 55, 1263–1269 (2019). https://doi.org/10.1134/S207020511907013X

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Keywords:

  • zero-charge potential
  • transition metals
  • anode processes
  • nonaqueous solvents