Thermally Stimulated Evolution of the Surface of Ni- and Cu-Containing Plasma-Electrolytic Oxide Coatings on Titanium

  • V. S. RudnevEmail author
  • I. V. Lukiyanchuk
  • M. S. Vasilyeva
  • A. A. Zvereva


The effect of the temperature of annealing in air on the surface architecture and composition of oxide layers has been studied. Copper-enriched nanosized crystals of triangular shape are present on the surface at the annealing temperatures of 500–700°С. Rectangular nano- and microcrystals of a possible composition of NiWO4 are formed on the surface after annealing at 750–850°С. Nanowhisker brushes, similar in composition to nickel titanates, cover the surface after annealing at 900–950°С. Transformation of the surface architecture and composition on the micro- and nanolevels correlates to the coatings’ activity in the catalysis of the reaction of oxidation of CO to CO2.


plasma electrolytic oxidation titanium coatings oxidation annealing surface architecture nano- and microformations 



The present work was partially supported by grant from the Russian Foundation for Basic Research no. 18-03-00418.


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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • V. S. Rudnev
    • 1
    • 2
    Email author
  • I. V. Lukiyanchuk
    • 1
  • M. S. Vasilyeva
    • 1
    • 2
  • A. A. Zvereva
    • 1
  1. 1.Institute of Chemistry, Far East Branch, Russian Academy of SciencesVladivostokRussia
  2. 2.Far Eastern Federal UniversityVladivostokRussia

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