The Adsorption of 5,10,15,20-Tetrakis(N-methylpyridyl-4')porphine Tetratosylate on the Surface of Nickel from an Aqueous Solution

  • N. P. AndreevaEmail author
  • A. V. Larionov
  • O. Yu. Grafov
  • O. A. Golubchikov
  • L. P. Kazanskii
  • Yu. I. Kuznetsov


Macroheterocyles, such as porphyrins, phthalocyanines, and their coordination compounds, introduced into standard electrolytes for nickel plating and electroplating of Ni–Co and Ni–Fe alloys substantially improve the quality of coatings. The adsorption of 5,10,15,20-tetrakis(N-methylpyridyl-4')porphine tetratosylate on the surface of Ni is studied via ellipsometry and X-ray photoelectron spectroscopy (XPS).


macroheterocylic compounds porphyrins phthalocyanines ellipsometry XPS 



This work was supported by the Russian Science Foundation (agreement no. 14-23-00204, grant no. 16-03-00646) and within the framework of the execution of a state order of the Ministry of Education and Science of the Russian Federation to institutions of higher education.


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • N. P. Andreeva
    • 1
    Email author
  • A. V. Larionov
    • 2
  • O. Yu. Grafov
    • 1
  • O. A. Golubchikov
    • 2
  • L. P. Kazanskii
    • 1
  • Yu. I. Kuznetsov
    • 1
  1. 1.A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of SciencesMoscowRussia
  2. 2.Scientific and Research Institute of Macroheterocycles, Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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