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The Effect of Phosphoryl–Substituted Porphyrins on Mobility of Charge Carriers in P3HT Polymer Photoconductor

  • A. R. TameevEmail author
  • A. R. Yusupov
  • A. V. Vannikov
  • M. G. Tedoradze
  • Yu. Yu. Enakieva
  • Yu. G. Gorbunova
  • A. Yu. Tsivadze
MOLECULAR AND SUPRAMOLECULAR STRUCTURES AT THE INTERFACES
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Abstract

The effect of additives of sensitizing Zn(II) and Co(II) complexes with 5,15-(diethoxyphosphoryl)-10,20-diphenylporphyrin on the mobility of holes in thin poly3-hexylthiophene films is studied. The charge carrier mobility is measured using the CELIV and photo-CELIV methods. It is found that the sensitizing additive does not affect the mobility of the equilibrium charge carriers, but causes a decrease in the mobility of the nonequilibrium charge carriers.

Notes

ACKNOWLEDGMENTS

This work was financially supported by Program 38P of the Presidium of Russian Academy of Sciences and a grant of the President of the Russian Federation for State Support of Leading Scientific Schools of the Russian Federation, NSh-3867.2018.3.

REFERENCES

  1. 1.
    Mylnikov, V. and Terenin, A., Mol. Phys., 1964, vol. 8, p. 387.Google Scholar
  2. 2.
    Yella, A., Lee, H.-W., Tsao, H.N., et al., Science, 2011, vol. 334, p. 629.Google Scholar
  3. 3.
    Yella, A., Mai, C.-L., Zakeeruddin, S.M., et al., Angew. Chem., Int. Ed. Engl., 2014, vol. 53, p. 2973.Google Scholar
  4. 4.
    Zervaki, G.E., Roy, M.S., Panda, M.K., et al., Inorg. Chem., 2013, vol. 52, p. 9813.Google Scholar
  5. 5.
    Bessmertnykh-Lemeune, A.G. and Guilard, R., in Supramolecular Systems: Chemistry, Types and Applications, Pena C., Ed., Nova Science, 2016, p. 213.Google Scholar
  6. 6.
    Uvarova, M.A., Sinelshchikova, A.A., Golubnichaya, M.A., et al., Cryst. Growth Des., 2014, vol. 14, p. 5976.Google Scholar
  7. 7.
    Sinelshchikova, A.A., Nefedov, S.E., Enakieva, Y.Y., et al., Inorg. Chem., 2013, vol. 52, p. 999.Google Scholar
  8. 8.
    Stern, C., Bessmertnykh-Lemeune, A.G., Gorbunova, Y.G., et al., Turk. J. Chem., 2014, vol. 38, p. 980.Google Scholar
  9. 9.
    Enakieva, Y.Y., Bessmertnykh-Lemeune, A.G., Gorbunova, Y.G., et al., Org. Lett., 2009, vol. 11, p. 3842.Google Scholar
  10. 10.
    Vinogradova, E.V., Enakieva, Y.Y., Nefedov, S.E., et al., Chem. - Eur. J., 2012, vol. 18, p. 15 092.Google Scholar
  11. 11.
    Enakieva, Y.Y., Michalak, J., Abdulaeva, I.A., et al., Eur. J. Org. Chem., 2016, vol. 2016, p. 4881.Google Scholar
  12. 12.
    Enakieva, Y.Y., Volostnykh, M.V., Nefedov, S.E., et al., Inorg. Chem., 2017, vol. 56, p. 3055.Google Scholar
  13. 13.
    Kadish, K.M., Chen, P., Enakieva, Y.Y., et al., J. Electroanal. Chem., 2011, vol. 656, p. 61.Google Scholar
  14. 14.
    Fang, Y., Kadish, K.M., Chen, P., et al., J. Porphyrins Phthalocyanines, 2013, vol. 17, p. 1035.Google Scholar
  15. 15.
    Fang, Y., Gorbunova, Y.G., Chen, P., et al., Inorg. Chem., 2015, vol. 54, p. 3501.Google Scholar
  16. 16.
    Zubatyuk, R.I., Sinelshchikova, A.A., Enakieva, Y.Y., et al., CrystEngComm, 2014, vol. 16, p. 10 428.Google Scholar
  17. 17.
    Mozer, A.J., Sariciftci, N.S., Pivrikas, A., et al., Phys. Rev. B, 2005, vol. 71, p. 35 214.Google Scholar
  18. 18.
    Yusupov, A.R., Tameev, A.R., Lachinov, A.N., et al., Technical Phys. Lett., 2013, vol. 39, p. 20.Google Scholar
  19. 19.
    Mozer, A.J., Sariciftci, N.S., Lutsen, L., et al., Appl. Phys. Lett., 2005, vol. 86, p. 112 104.Google Scholar
  20. 20.
    Al-Ibrahim, M., Roth, H.-Klaus, Zhokhavets, U., et al., Sol. Energy Mater. Sol. Cells, 2004, vol. 85, p. 13.Google Scholar
  21. 21.
    Gong, X., Tong, M., Brunetti, F.G., et al., Adv. Mater., 2011, vol. 23, p. 2272.Google Scholar
  22. 22.
    Choulis, S.A., Kim, Y., Nelson, J., et al., Appl. Phys. Lett., 2004, vol. 85, p. 3890.Google Scholar
  23. 23.
    Chan, K.K.H., Tsang, S.W., Lee, H.K.H., et al., Org. Electron.: Physics, Mater. Appl., 2012, vol. 13, p. 850.Google Scholar
  24. 24.
    Hirao, A., Tsukamoto, T., and Nishizawa, H., Phys. Rev. B, 1999, vol. 59, p. 12 991.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. R. Tameev
    • 1
    Email author
  • A. R. Yusupov
    • 2
  • A. V. Vannikov
    • 1
  • M. G. Tedoradze
    • 1
  • Yu. Yu. Enakieva
    • 1
  • Yu. G. Gorbunova
    • 1
    • 3
  • A. Yu. Tsivadze
    • 1
    • 3
  1. 1.Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of SciencesMoscowRussia
  2. 2.Akmulla Bashkir State Pedagogical UniversityUfaRussia
  3. 3.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia

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