The Effect of Phosphoryl–Substituted Porphyrins on Mobility of Charge Carriers in P3HT Polymer Photoconductor

  • A. R. TameevEmail author
  • A. R. Yusupov
  • A. V. Vannikov
  • M. G. Tedoradze
  • Yu. Yu. Enakieva
  • Yu. G. Gorbunova
  • A. Yu. Tsivadze


The effect of additives of sensitizing Zn(II) and Co(II) complexes with 5,15-(diethoxyphosphoryl)-10,20-diphenylporphyrin on the mobility of holes in thin poly3-hexylthiophene films is studied. The charge carrier mobility is measured using the CELIV and photo-CELIV methods. It is found that the sensitizing additive does not affect the mobility of the equilibrium charge carriers, but causes a decrease in the mobility of the nonequilibrium charge carriers.



This work was financially supported by Program 38P of the Presidium of Russian Academy of Sciences and a grant of the President of the Russian Federation for State Support of Leading Scientific Schools of the Russian Federation, NSh-3867.2018.3.


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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. R. Tameev
    • 1
    Email author
  • A. R. Yusupov
    • 2
  • A. V. Vannikov
    • 1
  • M. G. Tedoradze
    • 1
  • Yu. Yu. Enakieva
    • 1
  • Yu. G. Gorbunova
    • 1
    • 3
  • A. Yu. Tsivadze
    • 1
    • 3
  1. 1.Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of SciencesMoscowRussia
  2. 2.Akmulla Bashkir State Pedagogical UniversityUfaRussia
  3. 3.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia

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