Synthesis and Structural-Energy Characteristics of Fe-BDC Metal-Organic Frameworks
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A metal-organic framework, Fe-BDC, was synthesized by solvothermal method from iron salt and terephthalic acid using N,N-dimethylformamide as the solvent. The data from the study of structural-energy characteristics calculated by the Dubinin-Radushkevich, Kelvin, and BET equations are given. The resulting Fe-BDC sample has a specific surface area of SBET = 2240 m2/g and a specific micropore volume of W0 = 0.83 cm3/g. The morphological and X-ray characteristics of this sample were studied.
Keywords:metal-organic framework MOF iron BDC adsorption micropores mesopores
The contribution of the Center for Collective Use of Physical Methods of Investigation (Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences) is gratefully acknowledged.
- 16.Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Foundations of Adsorption Technique), Moscow: Khimiya, 1976.Google Scholar
- 17.Dubinin, M.M., Adsorbtsiya i poristost' (Adsorption and Porosity), Moscow: Military Academy of Chemical Defense Named after Marshal of the USSR S.K. Timoshenko, 1972.Google Scholar
- 18.Eksperimental'nye metody v adsorbtsii i molekulyarnoi khromatografii (Experimental Methods for Adsorption and Molecular Chromatography), Kiselev, A.V. and Dreving, V.P., Eds., Moscow: Moscow State Univ., 1973.Google Scholar
- 19.Shiryaev, A.A., Voloshchuk, A.M., Volkov, V.V., et al., J. Phys., 2017, vol. 848, p. 012009.Google Scholar
- 21.Shkolin, A.V. and Fomkin, A.A., Measurement Techniques, 2018, vol. 61, pp. 395–401.Google Scholar
- 25.Vemuri, R.S., Armatis, P.D., Bontha, J.R., et al., J. Bioterrorism Biodef., 2015, vol. 6, p. 137.Google Scholar