Advertisement

Synthesis and Structural-Energy Characteristics of Fe-BDC Metal-Organic Frameworks

  • M. K. KnyazevaEmail author
  • A. V. Shkolin
  • A. A. Fomkin
  • A. Yu. Tsivadze
  • O. V. Solovtsova
  • N. P. Platonova
  • A. L. Pulin
  • I. E. Men’shchikov
  • A. A. Shiryaev
  • V. V. Vysotskii
  • M. R. Kiselev
PHYSICOCHEMICAL PROCESSES AT THE INTERFACES
  • 17 Downloads

Abstract

A metal-organic framework, Fe-BDC, was synthesized by solvothermal method from iron salt and terephthalic acid using N,N-dimethylformamide as the solvent. The data from the study of structural-energy characteristics calculated by the Dubinin-Radushkevich, Kelvin, and BET equations are given. The resulting Fe-BDC sample has a specific surface area of SBET = 2240 m2/g and a specific micropore volume of W0 = 0.83 cm3/g. The morphological and X-ray characteristics of this sample were studied.

Keywords:

metal-organic framework MOF iron BDC adsorption micropores mesopores 

Notes

ACKNOWLEDGMENTS

The contribution of the Center for Collective Use of Physical Methods of Investigation (Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences) is gratefully acknowledged.

REFERENCES

  1. 1.
    Uzun, A. and Keskin, S., Prog. Surf. Sci., 2014, vol. 89, p. 56.CrossRefGoogle Scholar
  2. 2.
    Llewellyn, P.L., Bourrelly, S., Serre, C., et al., Langmuir, 2008, vol. 24, p. 7245.CrossRefGoogle Scholar
  3. 3.
    Krishna, R. and Baten, J.M., Sep. Purif. Technol., 2012, vol. 87, p. 120.CrossRefGoogle Scholar
  4. 4.
    Alhamami, M., Doan, H., and Cheng, C.-H., Materials, 2014, vol. 7, p. 3198.CrossRefGoogle Scholar
  5. 5.
    Sabouni, R., Kazemian, H., and Rohani, S., Environ. Sci. Pollut. Res. Int., 2014, vol. 21, p. 5427.CrossRefGoogle Scholar
  6. 6.
    Zhao, D., Yuan, D., and Zhou, H.-C., Energy Environ. Sci., 2008, vol. 1, p. 222.CrossRefGoogle Scholar
  7. 7.
    Sculley, J., Yuan, D., and Zhou, H.-C., Energy Environ. Sci., 2011, vol. 4, p. 2721.CrossRefGoogle Scholar
  8. 8.
    Falcaro, P., Ricco, R., Doherty, C.M., Liang, K., et al., Chem. Soc. Rev., 2014, vol. 43, p. 5513.CrossRefGoogle Scholar
  9. 9.
    Howarth, J., Liu, Y., Li, P., et al., Nat. Rev. Mater., 2016, vol. 1, p. 15 018.CrossRefGoogle Scholar
  10. 10.
    Agustaa, M.K., Saputroa, A.G., Tanuwijayaa, V.V., et al., Procedia Eng., 2017, vol. 170, p. 136.CrossRefGoogle Scholar
  11. 11.
    Kayal, S., Sun, B., and Chakraborty, A., Energy, 2015, vol. 91, p. 772.CrossRefGoogle Scholar
  12. 12.
    Chowdhury, P., Bikkina, C., and Gumma, S., J. Phys. Chem. C, 2009, vol. 113, p. 6616.CrossRefGoogle Scholar
  13. 13.
    Hong, D.Y., Hwang, Y.K., Serre, C., et al., Adv. Funct. Mater., 2009, vol. 19, p. 1537.CrossRefGoogle Scholar
  14. 14.
    Horcajada, P., Chevreau, H., Heurtaux, D., et al., Chem. Commun., 2014, vol. 50, p. 6872.CrossRefGoogle Scholar
  15. 15.
    Senkovska, I., Hoffmann, F., Fröba, M., Kaskel, S., et al., Microporous Mesoporous Mater., 2009, vol. 122, p. 93.CrossRefGoogle Scholar
  16. 16.
    Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Foundations of Adsorption Technique), Moscow: Khimiya, 1976.Google Scholar
  17. 17.
    Dubinin, M.M., Adsorbtsiya i poristost' (Adsorption and Porosity), Moscow: Military Academy of Chemical Defense Named after Marshal of the USSR S.K. Timoshenko, 1972.Google Scholar
  18. 18.
    Eksperimental'nye metody v adsorbtsii i molekulyarnoi khromatografii (Experimental Methods for Adsorption and Molecular Chromatography), Kiselev, A.V. and Dreving, V.P., Eds., Moscow: Moscow State Univ., 1973.Google Scholar
  19. 19.
    Shiryaev, A.A., Voloshchuk, A.M., Volkov, V.V., et al., J. Phys., 2017, vol. 848, p. 012009.Google Scholar
  20. 20.
    Zhigalina, V., Zhigalina, O., Ponomarev, I., et al., CrystEngComm, 2017, vol. 19, p. 3792.CrossRefGoogle Scholar
  21. 21.
    Shkolin, A.V. and Fomkin, A.A., Measurement Techniques, 2018, vol. 61, pp. 395–401.Google Scholar
  22. 22.
    Ferey, G., Mellot-Draznieks, C., Serre, C., et al., Science, 2005, vol. 309, p. 2040.CrossRefGoogle Scholar
  23. 23.
    Kholdeeva, O.A., Skobelev, I.Y., Ivanchikova, I.D., et al., Catal. Today, 2014, vol. 238, p. 54.CrossRefGoogle Scholar
  24. 24.
    Taylor-Pashow, K.M.L., Xie, Z., Tran, S., et al., J. Am. Chem. Soc., 2009, vol. 131, p. 14261.CrossRefGoogle Scholar
  25. 25.
    Vemuri, R.S., Armatis, P.D., Bontha, J.R., et al., J. Bioterrorism Biodef., 2015, vol. 6, p. 137.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • M. K. Knyazeva
    • 1
    Email author
  • A. V. Shkolin
    • 1
  • A. A. Fomkin
    • 1
  • A. Yu. Tsivadze
    • 1
  • O. V. Solovtsova
    • 1
  • N. P. Platonova
    • 1
  • A. L. Pulin
    • 1
  • I. E. Men’shchikov
    • 1
  • A. A. Shiryaev
    • 1
  • V. V. Vysotskii
    • 1
  • M. R. Kiselev
    • 1
  1. 1.Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of SciencesMoscowRussia

Personalised recommendations