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Adsorption and inhibitive effect of Schinus terebinthifolius extract as a green corrosion inhibitor for carbon steel in acidic solution

  • K. Shalabi
  • Ahmed Abdel NazeerEmail author
Physicochemical Problems of Materials Protection

Abstract

The effect of Egyptian Schinus-terebinthifolius extract (STE) on carbon steel corrosion in 0.5 M HCl solution was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), electrochemical frequency modulation (EFM), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) techniques. The results show that STE is a good inhibitor in 0.5 M HCl. The adsorption of STE obeys Langmuir adsorption isotherm. STE acts as mixed-type but mainly cathodic inhibitor in 0.5 M HCl. The thermodynamic parameters of the corrosion process were calculated and discussed. Maximum inhibition approached 93.3% at 900 ppm STE. SEM showed the Protective film formation on steel surface in presence of STE.

Keywords

Carbon Steel Electrochemical Impedance Spectroscopy Inhibition Efficiency Potentiodynamic Polarization Constant Phase Element 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of ScienceMansoura UniversityMansoura-Egypt
  2. 2.Electrochemistry and Corrosion Lab.National Research CentreDokki, Cairo-Egypt

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