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Polymer Science, Series D

, Volume 12, Issue 1, pp 64–68 | Cite as

Copolymerization of 2-Hydroxyethyl Methacrylate with Carboxylic Monomers

  • N. A. LavrovEmail author
Article
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Abstract

The results of experimental studies on copolymerization kinetics of 2-hydroxyethyl methacrylate with carboxyl-containing monomers of acrylic, methacrylic, and maleic acids in water using the redox initiator system of ammonium persulfate–ascorbic acid are summarized. The effect of process conditions on the reaction rate, relative activity of monomers, composition, and microstructure of copolymers is analyzed.

Keywords:

2-hydroxyethyl methacrylate acrylic acid methacrylic acid maleic acid copolymerization kinetics constants of relative activity of monomers microstructure of copolymers 

Notes

REFERENCES

  1. 1.
    S. N. Ushakov, Synthetic Medicinal Polymers (Medgiz, Leningrad, 1962) [in Russian].Google Scholar
  2. 2.
    E. F. Panarin, “Biologically active polymer nanosystems,” Russ. Chem. Bull. 66 (10), 1812–1820 (2017).Google Scholar
  3. 3.
    M. V. Solovskii, G. M. Pavlov, E. V. Korneeva, S. E. Harding, V. M. Denisov, and N. V. Nikol’skaya, “Synthesis of N-vinylpyrrolidone-crotonic acid-2-hydroxyethyl methacrylate terpolymers as carriers of biologically active substances,” Russ. J. Appl. Chem. 75 (2), 276–280 (2002).Google Scholar
  4. 4.
    N. A. Lavrov, “Properties of 2-hydroxyethylmethacrylate copolymers and hydrogels based on them,” Polym. Sci., Ser. D 5 (2), 77–82 (2012).Google Scholar
  5. 5.
    K. K. Kalnin’sh and L. P. Pavlova, Water—A Spring of Life: Monograph (Inst. Vysokomol. Soedin. Ross. Akad. nauk, S.-Peterb. Gos. Univ. Tekhnol. Dizaina, St. Petersburg, 2005) [in Russian].Google Scholar
  6. 6.
    N. A. Lavrov, “Kinetic features of the homopolymerisation of 2-hydroxyethylmethacrylate in various media,” Int. Polym. Sci. Technol. 31 (5), 44–59 (2004).Google Scholar
  7. 7.
    N. A. Nesterova, I. N. Gavrilova, and E. F. Panarin, “Radical copolymerization of N-vinylformamide with unsaturated carboxylic acids,” Russ. J. Appl. Chem. 82 (4), 618–621 (2009).Google Scholar
  8. 8.
    M. V. Solovskii, M. Yu. Eropkin, M. Yu. Smirnova, and I. I. Gavrilova, “Complexes of antibiotics-aminoglycosides with copolymers of acrylamide with acrylic and methacrylic acids,” Pharm. Chem. J. 44 (6), 314–318 (2010).Google Scholar
  9. 9.
    A. F. Nikolaev, Structure and Properties of Water (S.‑Peterb. Gos. Tekhnol. Inst., St. Petersburg, 2006) [in Russian].Google Scholar
  10. 10.
    N. A. Lavrov, “Theoretical and practical aspects of the synthesis of medical polymers based on nvinylsuccinimide in aqueous media,” Int. Polym. Sci. Technol. 39 (1), 47–60 (2012).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.St. Petersburg State Institute of Technology (Technical University)St. PetersburgRussia

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