Abstract
High-purity, regularly shaped nanostructured gold-carbon composites with high specific surface area and porosity were obtained via the reduction of hydrogen tetrachloroaurate (III) by highly porous matrices developed with the authors’ participation. The effect of gold content and porous structure parameters of matrices on the formation topography, size and shape of filler particles, and parameters of the porous structure of gold-carbon composites was studied. It was revealed that surface the decoration of matrix pores with gold particles takes place as HAuCl4 is reduced by Kemerit and Carbonizat highly porous carbon matrices.
Similar content being viewed by others
References
A. K. Gatin, M. V. Grishin, A. A. Kirsankin, V. A. Kharitonov, and B. R. Shub, “Individual nanoparticles of aluminum, gold, nickel, and platinum deposited on a pyrolytic graphite surface,” Nanotech. Russ. 8(1–2), 36 (2013).
V. K. Portnoi, A. V. Leonov, A. I. Logacheva, A. V. Logachev, and A. N. Streletskii, “Mechanochemical synthesis and compaction of nanocomposites based on Ni3Al intermetallic compound containing carbon and carbide-forming elements,” Nanotech. Russ. 8(11–12), 773 (2013).
D. B. Akolekar and S. K. Bhargava, “Investigations on gold nanoparticles in mesoporous and microporous materials,” J. Molec. Catal. A: Chem. 236, 77–86 (2005).
J. Jiao and S. Seraphin, “Single-walled tubes and encapsulated nanoparticles: comparison of structural properties of carbon nanoclusters prepared by three different methods,” J. Phys. Chem. Solids 61, 1055–1067 (2000).
V. V. Sviridov, T. N. Vorob’eva, T. V. Gaevskaya, and L. I. Stepanova, Metals Chemical Deposition in Aqueous Solutions (Univ., Minsk, 1987) [in Russian].
K. M. Vansovskaya, Chemically Deposited Metallic Coatings (Mashinostroenie, Leningrad, 1985) [in Russian].
V. F. Puntes, K. Krishnan, and A. P. Alivisatos, “Synthesis of colloidal cobalt nanoparticles with controlled size and shapes,” Top. Catal. 19(2), 145–148 (2002).
F. Dumur, A. Guerlin, E. Dumas, D. Bertin, D. Gigmes, and C. R. Mayer, “Controlled spontaneous generation of gold nanoparticles assisted by dual reducing and capping agent,” Gold Bull. 44(2), 119–137 (2011).
A. I. Busev, and V. M. Ivanov, Analytical Chemistry of Gold (Nauka, Moscow, 1973) [in Russian].
L. A. Dykman, V. A. Bogatyrev, S. Yu. Shchegolev, and N. G. Khlebtsov, Golden Nanoparticles: Synthesis, Properties, Biomedical Application (Nauka, Moscow, 2008) [in Russian].
M. Faraday, “The Bakerian lecture: experimental relations of gold (and other metals) to light,” Philos. Trans. Roy. Soc. 147, 145–181 (London, 1857).
Y. Sanokawa, D. Uchida, Y. Kude, and T. Kobayashi, Japan Patent No. 2000191386. IPC7; C 04 B 35/52; C 04 B 41/51; C 04 B 41/88 (11.07.2000).
D. H. Bae and H. J. Choi, US Patent No. 2012241670. IPC7; C 09 K 3/00; C 22 C 1/02; C 22 C 1/05 (27. 09. 2012).
T. K. Shah, H. C. Malecki, and J. A. Waicukauski, US Patent No. 2012164429. IPC7; B 22 D 19/14; B 22 D 25/00; B 22 F 3/00 (28.06.2012).
J. V. Shugart and R. C. Scherer, US Patent No. 2012009110. IPC7; C 01 B 31/30 (12.01.2012).
T. J. Konno, K. Shoji, K. Sumiyama, and K. Suzuki, “Structure and magnetic properties of co-sputtered Co-C thin films,” J. Magn. Magn. Mater. 195, 9–18 (1999).
N. Sano, H. Akazawa, T. Kikuchi, and T. Kanki, “Separated synthesis of iron-included carbon nanocapsules and nanotubes by pyrolysis of ferrocene in pure hydrogen,” Carbon 41(11), 2159–2179 (2003).
Z. H. Wang, Z. D. Zhang, C. J. Choi, and B. K. Kim, “Structure and magnetic properties of Fe(C) and Co(C) nanocapsules prepared by chemical vapor condensation,” J. Alloys Compounds 361, 289–293 (2003).
K. A. Bagdasarova, “Metal-carbon magnetic nanocomposites based on infrared pyrolyzed polyacrylnitride,” Extended Abstract of Candidate’s Dissertation in Physical and Mathematical Sciences (Moscow, 2008).
K. A. Bagdasarova, L. M. Zemtsov, G. N. Karpacheva, et al., “Structure and magnetic properties of metal-carbon nanocomosites based on infrared pyrolyzed polyacrylnitride and Fe,” Fiz. Tverd. Tela 50(4), 739–742 (2008).
M. N. Efimov, E. L. Dzidziguri, E. N. Sidorova, et al., “Phase formation in nanocomposites of the C-Pd-Fe system,” Russ. J. Phys. Chem. A. 85(4), 660 (2011).
M. N. Efimov, A. A. Nekrasova, E. L. Dzidziguri, et al., “Variation in palladium nanoparticles structure in C-Pd system under hydrogen dissipation,” Kristallografiya 57(4), 638–642 (2012).
E. L. Dzidziguri, D. G. Muratov, L. M. Zemtsov, et al., “Formation of bimetal nanoparticles in the structure of C-Cu-Zn metal-carbon nanocomposite,” Nanotech. Russ. 7(1–2), 62 (2012).
V. A. Bogatyrev, L. A. Dykman, and N. G. Khlebtsov, The Way to Synthesize Nanoparticels with Plasmonic Resonance (Saratov State Univ., Saratov, 2009) [in Russian].
A. Yu. Olenin and G. V. Lisichkin, “The way to produce, structure dynamics of volume and surface of metallic nanoparticles in condensed mediums,” Usp. Khim. 80(7), 635–662 (2011).
S. Guoyue, C. Junshui, X. Sujie, X. He, L. Ying, N. Dongxia, W. Yinyin, S. Qian, and J. Litong, China Patent No. 102033088. IPC7; G 01 N 27/30; G 01 N 27/48 (27.04.11).
S. Kumar, I. Kaur, K. Dharamvir, and L. M. Bharadwaj, “Controlling the density and site of attachment of gold nanoparticles onto the surface of carbon nanotubes,” J. Colloid Interface Sci. 369, 23–27 (2012).
X. Hou, L. Wang, X. Wang, and Z. Li, “Coating multiwalled carbon nanotubes with gold nanoparticles derived from gold salt precursors,” Diamond Related Mater. 20, 1329–1332 (2011).
L. Jiang and L. Gao, “Modified carbon nanotubes: an effective way to selective attachment of gold nanoparticles,” Carbon 41(15), 2923–2929 (2003).
K. M. Metz, P. E. Colavital, K.-Y. Tse, and R. J. Hamers, “Nanotextured gold coatings on carbon nanofiber scaffolds as ultrahigh surface-area electrodes,” J. Power Sources 198, 393–401 (2012).
N. V. Pavelko, G. Yu. Simenyuk, T. S. Manina, et al., “The way to produce nanostructures metal-carbon composites based on carbon matrixes,” Vestn. Kemerovsk. Gos. Univ. 3(3), 100–104 (2013).
N. V. Pavelko, G. Yu. Simenyuk, T. S. Manina, and Yu. A. Zakharov, “Nanostructured metal-carbon composites based on gold and mesoporous carbon matrixes,” in Proc. 20th Int. Chernyaev Conf. on Chemistry, Analytics and Technology of Platinum Metals (Siberian Federal Univ., Krasnoyarsk, 2013), p. 211.
A. V. Samarov, Ch. N. Barnakov, A. P. Kozlov, and Z. R. Ismagilov, “The way to produce highly porous materials (sorbets) from coals, cokes and individual organic compounds for methane adsorption storage,” Koks Khim., No. 09, 29–34 (2012).
Ch. N. Barnakov, S. K. Seit-Ablaeva, A. P. Kozlov, et al., RF Patent No. 2206394. IPC7 B01 J20/20, C01 B31/12 (2002).
T. S. Manina, N. I. Fedorova, S. A. Semenova, and Z. R. Ismagilov, “The way to process low-grade oxygenated coals for producing highly efficient carbon sorbents,” Koks Khim., No. 03, 43–46 (2012).
D. I. Cvergun and L. A. Feigin, X-Ray and Neutron Low-Angle Scattering (Nauka, Moscow, 1986) [in Russian].
A. R. West, Solid State Chemistry and Its Applications (Wiley, Chichester, 1984), Part 1.
S. S. Gorelik, Yu. A. Skakov, and L. N. Rastorguev, X-Ray Diffraction and Electron-Optical Analyses (National Univ. of Science and Technology MISiS, Moscow, 1994).
L. M. Plyasova, Introduction into Catalytic Agents X-Ray Radiography (Boreskov Institute of Catalysis Siberian Branch RAS, Novosibirsk, 2010) [in Russian].
E. L. Dzidziguri and E. N. Sidorova, Ultrafine Mediums: Methods of X-Ray Diffractometry for Nanomaterials Research (National Univ. of Science and Technology MISiS, Moscow, 2007) [in Russian].
E. L. Dzidziguri, “The way to research nanomaterials by means of X-ray diffractometry,” Nanotekhnol. Nauka Proizv., Special Issue, 91–95 (2012).
V. G. Dodonov, “The improved method of particle size distribution analysis from the small-angle X-ray scattering data,” Z. Kristallogr. Suppl. Issue, No. 4, 102 (1991).
V. G. Dodonov, “The way to apply low-angle scattering for analyzing inhomogeneous material structure. Applied software pack,” in Proc. 9th Int. Conf. on Radiation Physics and Chemistry of Inorganic Materials (Tomsk Polytech. Univ., Tomsk, 1996), pp. 139–140 [in Russian].
A. P. Karnaukhov, Absorption. Texture of Dispersed and Porous Materials (Nauka, Novosibirsk, 1999) [in Russian].
S. J. Gregg and K. S. W. Sing, Adsorption, Surface Area and Porosity (Acad., London, 1967).
L. V. Adamova and A. P. Safronov, Sorption Method for Researching Nanomaterials’ Porous Structure and Specific Surface of Nanosized Systems. Student’s Book (Ural State Univ., Yekaterinburg, 2008) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Yu.A. Zakharov, G.Yu. Simenyuk, V.M. Pugachev, V.G. Dodonov, N.V. Pavelko, T.S. Manina, Ch.N. Barnakov, 2015, published in Rossiiskie Nanotekhnologii, 2015, Vol. 10, Nos. 5–6.
Rights and permissions
About this article
Cite this article
Zakharov, Y.A., Simenyuk, G.Y., Pugachev, V.M. et al. Nanostructured composites based on highly porous carbon matrices filled with gold. Nanotechnol Russia 10, 388–399 (2015). https://doi.org/10.1134/S1995078015030192
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1995078015030192