Abstract
The curing process was studied for compositions of diepoxide 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, SiO2 nanoparticles with grafted glycidyl groups, and a curing agent based on methyltetrahydrophthalic anhydride. It is shown that optically transparent epoxy composites with higher heat resistance can be obtained in the presence of a nanofiller. The softening temperature T soft of these composites coincides with the onset of thermal degradation at 325°C.
Similar content being viewed by others
References
A. E. Batog, T. V. Savenko, and I. P. Pet’ko, Aliphatic Acyclic Epoxides: Synthesis, Properties of Polymer and Composite Materials on Their Base. Plastic Manufacturing and Processing (NIITEKhIM, Moscow, 1991), p. 53 [in Russian]
I. Sh. Pik, Plastics Technology (Khimiya, Leningrad, 1975) [in Russian].
N. P. Kharitonov and I. A. Shentenkova, Heatproof Organosilicate Sealants (Nauka, Leningrad, 1977), p. 29 [in Russian].
V. K. Skachkova, A. B. Gil’man, N. A. Shmakova, V. A. Optov, A. Yu. Shaulov, and A. A. Berlin, Khim. Vys. Energ. 42(6), 555 (2008).
V. K. Skachkova, A. B. Gil’man, N. A. Shmakova, V. A. Optov, A. Yu. Shaulov, and A. A. Berlin, in Proc. Sci. Conf. “Polymers-2008”. Section Polymers and Composite Materials (Moscow, March 2008), p. 51.
S. Kang, S. I. Hong, C. R. Choe, M. Park, S. Rim, and J. Kim, Polymer 42(3), 879 (2001).
A. I. Barabanova, P. L. Shevnin, T. A. Pryakhina, K. A. Bychko, V. V. Kazantseva, B. G. Zavin, Ya. S. Vygodskii, A. A. Askadskii, O. E. Filippova, and A. R. Khokhlov, Vysokomol. Soed., Ser. A 50(7), 1242 (2008).
V. K. Skachkova, A. V. Lyubimov, G. V. Lyubimova, M. N. Gusev, A. V. Grachev, V. M. Lalayan, V. A. Matyshak, and A. Yu. Shaulov, in Proc. 10th Int. Conf. on Oligomers Chemistry and Physical Chemistry “Oligomers-2009” (Volgograd, Sept. 7–11, 2009), p. 248.
L. G. Nechitailo, M. Z. Reznikova, I. M. Shologon, and M. K. Pakter, IR-Spectroscopy for Epoxy Resins (NIITEKhIM, Moscow, 1988), p. 42 [in Russian].
J. Dehant, R. Danz, W. Kimmer, and R. Schmolke, Ultrarotspektroskopische Untersuchungen an Polymeren (Akad. Verlag, Berlin, 1972; Khimiya, Moscow, 1976).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.K. Skachkova, A.V. Lyubimov, G.V. Lyubimova, M.N. Gusev, A.V. Grachev, V.M. Lalayan, A.Yu. Shaulov, A.A. Berlin, 2013, published in Rossiiskie Nanotekhnologii, 2013, Vol. 8, Nos. 1–2.
Rights and permissions
About this article
Cite this article
Skachkova, V.K., Lyubimov, A.V., Lyubimova, G.V. et al. Optically transparent heat-resistant nanocomposites based on epoxy resin and silicon dioxide. Nanotechnol Russia 8, 92–98 (2013). https://doi.org/10.1134/S199507801301014X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S199507801301014X